A molecular electron density theory study of Diels‐Alder reaction between Danishefsky's diene and (2E)‐3‐phenyl‐2‐(trifluoromethyl) acrylonitrile

2019 ◽  
Vol 32 (6) ◽  
pp. e3937
Author(s):  
Tooba Afshari ◽  
Mohsen Mohsennia
Keyword(s):  
Electron Density ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Molecular Electron ◽  
Molecular Electron Density Theory ◽  
Danishefsky's Diene

On the Catalytic Effects of the Thiazolium Salt in the Oxa-Diel-Alder Reaction between Benzaldehyde and Danishefsky’s Diene: A Molecular Electron Density Theory Study

2021 ◽  
Author(s):  
Mar Ríos-Gutiérrez ◽  
Patricia Perez ◽  
Luis R. Domingo ◽  
Jorge Soto-Delgado
Keyword(s):  
Ionic Liquid ◽  
Electron Density ◽  
Alder Reaction ◽  
Diels Alder ◽  
Molecular Electron ◽  
Molecular Electron Density Theory ◽  
Danishefsky's Diene ◽  
Catalytic Effects

The oxa-Diels-Alder (ODA) reaction of benzaldehyde with the Danishefsky diene in the presence of [thiazolium][Cl] salt, as a model of an ionic liquid, has been studied within Molecular Electron Density...

Enantioselective Diels–Alder Reaction of 3-Nitrocoumarins Promoted by Chiral Organoammonium Salt Catalysts

Synlett ◽  
2020 ◽  
Vol 31 (20) ◽  
pp. 2013-2017
Author(s):  
Akira Sakakura ◽  
Yudai Fujii ◽  
Ryota Nakao ◽  
Saki Sugihara ◽  
Keita Fujita ◽  
...  
Keyword(s):  
Amino Alcohol ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Danishefsky's Diene

AbstractAn enantioselective Diels–Alder reaction of 3-nitrocoumarins has been developed. A tryptophan-derived C 1-symmetric organoammonium thiourea catalyst promoted the reaction of 3-nitrocoumarins with Danishefsky’s diene to give the corresponding adducts with good enantioselectivity (up to 94% ee). One of the resulting adducts was converted into a chiral carbocyclic quaternary β-amino alcohol.

Insights into the stereoselective BF3-catalyzed hetero Diels–Alder reaction of Garner’s aldehyde with Danishefsky’s diene

2010 ◽  
Vol 21 (4) ◽  
pp. 398-404 ◽  
Author(s):  
Carolina Fontana ◽  
Marcelo Incerti ◽  
Guillermo Moyna ◽  
Eduardo Manta
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Danishefsky's Diene
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