Gas-phase equilibrium constants for the thermally initiated oxidation of hexafluoropropene with molecular oxygen

2015 ◽  
Vol 28 (7) ◽  
pp. 460-471 ◽  
Author(s):  
David Lokhat ◽  
Deresh Ramjugernath ◽  
Maciej Starzak
2005 ◽  
Vol 401 (4-6) ◽  
pp. 393-399
Author(s):  
Matthew F. Tuchler ◽  
Kierstin L. Schmidt ◽  
Mackenzie Morgan

2017 ◽  
Vol 43 (12) ◽  
pp. 7055-7071 ◽  
Author(s):  
Shengqiang Xu ◽  
Qingming Huang ◽  
Yanting Xu ◽  
Zhuoliang Ye ◽  
Xiaohui Chen

2012 ◽  
Vol 179 ◽  
pp. 285-294 ◽  
Author(s):  
Van-Huy Nguyen ◽  
Hsiang-Yu Chan ◽  
Jeffrey C.S. Wu ◽  
Hsunling Bai

The equilibrium constants of gas-phase complexes of HF with dimethyl, methyl ethyl and diethyl ether have been measured at several temperatures using the Benesi-Hildebrand approximation on the absorption band of the HF stretching vibration in the complex. From these, values of Δ H of — 43, — 38 and — 30 kJ mol -1 respectively, have been determined. They are interpreted in terms of conformational rearrangements of the ethers when they form hydrogen bonds. The far infrared spectra of the complexes with both HF and DF have also been recorded and in each case a band observed at around 180 cm -1 which is assigned to the intermolecular stretching mode of vibration. For the complex between HF and dimethyl ether a rotational contour has been observed at about 10 cm -1 .


2003 ◽  
Vol 5 (5) ◽  
pp. 956-965 ◽  
Author(s):  
Rei Hamada ◽  
Yusuke Shibata ◽  
Satoru Nishiyama ◽  
Shigeru Tsuruya

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