Formation of diazohydroxides ArN2 OH in aqueous acid solution: polarographic determination of the equilibrium constant K R for the reaction of 4-substituted arenediazonium ions with H2 O

2013 ◽  
Vol 27 (4) ◽  
pp. 284-289 ◽  
Author(s):  
Andrzej Sienkiewicz ◽  
Marta Szymula ◽  
Jolanta Narkiewicz-Michalek ◽  
Carlos Bravo-Díaz
Keyword(s):  
Acid Solution ◽  
Equilibrium Constant ◽  
Polarographic Determination ◽  
Aqueous Acid Solution ◽  
Aqueous Acid

scholarly journals AROMATIC SUBSTITUTION: PART IX. ON THE MECHANISM OF THE PSCHORR CYCLIZATION

1965 ◽  
Vol 43 (4) ◽  
pp. 940-949 ◽  
Author(s):  
R. A. Abramovitch ◽  
G. Tertzakian
Keyword(s):  
Acid Solution ◽  
Diazonium Salt ◽  
Equimolar Mixture ◽  
Diazonium Salts ◽  
Aromatic Substitution ◽  
Radical Process ◽  
Aqueous Acid Solution ◽  
Aqueous Acid ◽  
Catalyzed Reactions

The decomposition of the diazonium salt from 3-(o-aminobenzoyl)pyridine has been studied under various conditions. A competitive-type cyclization of an equimolar mixture of the diazonium salts of 2-aminobenzophenone and 2-amino-3′-nitrobenzophenone has also been carried out. The results are interpreted in terms of a radical process in the copper-catalyzed reactions. It is suggested that the uncatalyzed thermal decompositions in aqueous acid solution give rise to a diradical cation intermediate in equilibrium with the aryl cation.

A kinetic study of nonoxidative dissolution of galena in aqueous acid solution

1980 ◽  
Vol 11 (3) ◽  
pp. 377-381 ◽  
Author(s):  
Yasuhiro Awakura ◽  
Shinya Kamei ◽  
Hiroshi Majima
Keyword(s):  
Acid Solution ◽  
Kinetic Study ◽  
Aqueous Acid Solution ◽  
Aqueous Acid
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