scholarly journals Polymer grafting from a metallo‐centered enzyme improves activity in non‐native environments

2020 ◽  
Author(s):  
Marina Kovaliov ◽  
Borui Zhang ◽  
Dominik Konkolewicz ◽  
Katarzyna Szcześniak ◽  
Stefa Jurga ◽  
...  
2014 ◽  
Vol 93 ◽  
pp. 164-167 ◽  
Author(s):  
Joon Won Lim ◽  
Atta Ul Haq ◽  
Sang Ouk Kim

Polymer grafting from graphitic carbon materials has been explored for several decades. Currently existing methods mostly employ harsh chemical treatment to generate defect site in graphitic carbon plane, which are used as active site for polymerization of precursors. Unfortunately, the treatment cause serious degradation of chemical structure and material properties. Here, we present a straightforward route for growth of polyaniline chain from nitrogen (N)-sites of carbon nanotubes. N site in the CNT wall initiates the polymerization of aniline monomer, which generates seamless hybrids composed of polyaniline directly grafted onto the CNT walls. The synthesized hybrids show excellent synergistic electrochemical performance, and are employed for electrodes of pseudo-capacitor. This approach offers an efficient way to obtain hybrid system consisting of conducting polymers directly grafted from graphitic dopant sites.


Small ◽  
2007 ◽  
Vol 3 (7) ◽  
pp. 1230-1236 ◽  
Author(s):  
Ana C. C. Esteves ◽  
Lindsay Bombalski ◽  
Tito Trindade ◽  
Krzysztof Matyjaszewski ◽  
Ana Barros-Timmons

2016 ◽  
Vol 55 (49) ◽  
pp. 15306-15309 ◽  
Author(s):  
Ji Yup Kim ◽  
Bong Soo Lee ◽  
Jinsu Choi ◽  
Beom Jin Kim ◽  
Ji Yu Choi ◽  
...  

2016 ◽  
Vol 128 (49) ◽  
pp. 15532-15535 ◽  
Author(s):  
Ji Yup Kim ◽  
Bong Soo Lee ◽  
Jinsu Choi ◽  
Beom Jin Kim ◽  
Ji Yu Choi ◽  
...  

Soft Matter ◽  
2006 ◽  
Vol 2 (12) ◽  
pp. 1043 ◽  
Author(s):  
G. Carrot ◽  
A. El Harrak ◽  
J. Oberdisse ◽  
J. Jestin ◽  
F. Bou?

Soft Matter ◽  
2021 ◽  
Author(s):  
Vincent M. Torres ◽  
Jacob A. LaNasa ◽  
Bryan D. Vogt ◽  
Robert J. Hickey

In situ polymer grafting from the mid-block of an ABA triblock copolymer leads to morphology transitions and enhanced mechanical properties.


Langmuir ◽  
1992 ◽  
Vol 8 (5) ◽  
pp. 1392-1397 ◽  
Author(s):  
Rachel Yerushalmi-Rozen ◽  
Jacob Klein ◽  
Garry Berkovic

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