Pre‐thermal treatment in binary solvent systems promoting β crystalline phase of electrospun poly(vinylidene fluoride) nanofibers

2020 ◽  
Vol 69 (8) ◽  
pp. 719-727
Author(s):  
Praewpanit Nuamcharoen ◽  
Takaomi Kobayashi ◽  
Pranut Potiyaraj ◽  
Makoto Shiozaki
2017 ◽  
Vol 37 (1) ◽  
pp. 31-41 ◽  
Author(s):  
Chao Fu ◽  
Xuemei Wang ◽  
Xiang Shi ◽  
Xianghai Ran

Abstract Inorganic montmorillonite (MMT)/poly(vinylidene fluoride) nanocomposites were prepared by two methods: co-precipitation and solution casting. The effect of preparation methods and thermal treatment on crystalline phase was investigated by Fourier transform infrared spectroscopy and differential scanning calorimetry tests. The isothermal crystallization process was observed with polarized optical microscopy. It was found that the solution-casting method was more effective than the co-precipitation method in inducing the polar phase in the melt-isothermal crystallization process. The addition of inorganic MMT by the solution-casting method without further thermal treatment promoted the β-phase crystallization. The inorganic MMT significantly improved the γ phase of the solution-cast samples in the melt-recrystallization process. The degree of dispersion of inorganic MMT influenced the relative content of the polar phase and the crystallinity of the samples in the same crystallization conditions, i.e. the preparation method and the thermal treatment. The effect of dispersion on crystallization kinetics was also studied to verify the enhancement of finely dispersed nanolayer clusters on the γ phase.


Author(s):  
Ying Guo ◽  
Hui He ◽  
Haishuang Huang ◽  
Jingxuan Qiu ◽  
Jiaming Han ◽  
...  

CrystEngComm ◽  
2021 ◽  
Author(s):  
Yanpeng Zhao ◽  
Guanwen Su ◽  
Guozhao Liu ◽  
Hongyuan Wei ◽  
Leping Dang

The effects of thirteen binary solvent systems on the growth of CL-20 were studied by molecular dynamics simulation, and the effect of antisolvent properties on the solvent inhibition was systematically investigated.


Biopolymers ◽  
1968 ◽  
Vol 6 (7) ◽  
pp. 973-982 ◽  
Author(s):  
Akio Nakajima ◽  
Toshio Hayashi ◽  
Minako Ohmori

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