Electrically insulating polymeric nanocomposites with enhanced thermal conductivity by visible-light curing of epoxy-boron nitride nanotube formulations

2017 ◽  
Vol 66 (12) ◽  
pp. 1935-1939 ◽  
Author(s):  
Marco Sangermano ◽  
Nicolò Razza ◽  
Gabriele Graham ◽  
Irati Barandiaran ◽  
Galder Kortaberria
Keyword(s):  
Thermal Conductivity ◽  
Boron Nitride ◽  
Visible Light ◽  
Boron Nitride Nanotube ◽  
Polymeric Nanocomposites ◽  
Light Curing ◽  
Visible Light Curing ◽  
Enhanced Thermal Conductivity

scholarly journals 3D Printing of PDMS-Like Polymer Nanocomposites with Enhanced Thermal Conductivity: Boron Nitride Based Photocuring System

Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 373 ◽  
Author(s):  
Lorenzo Pezzana ◽  
Giacomo Riccucci ◽  
Silvia Spriano ◽  
Daniele Battegazzore ◽  
Marco Sangermano ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Thermal Analysis ◽  
Boron Nitride ◽  
Thermal Analyses ◽  
Tensile Tests ◽  
Morphological Characterization ◽  
Digital Light Processing ◽  
Form Complex ◽  
K Value ◽  
Enhanced Thermal Conductivity

This study demonstrates the possibility of forming 3D structures with enhanced thermal conductivity (k) by vat printing a silicone–acrylate based nanocomposite. Polydimethylsiloxane (PDSM) represent a common silicone-based polymer used in several applications from electronics to microfluidics. Unfortunately, the k value of the polymer is low, so a composite is required to be formed in order to increase its thermal conductivity. Several types of fillers are available to reach this result. In this study, boron nitride (BN) nanoparticles were used to increase the thermal conductivity of a PDMS-like photocurable matrix. A digital light processing (DLP) system was employed to form complex structures. The viscosity of the formulation was firstly investigated; photorheology and attenuate total reflection Fourier-transform infrared spectroscopy (ATR-FTIR) analyses were done to check the reactivity of the system that resulted as suitable for DLP printing. Mechanical and thermal analyses were performed on printed samples through dynamic mechanical thermal analysis (DMTA) and tensile tests, revealing a positive effect of the BN nanoparticles. Morphological characterization was performed by scanning electron microscopy (SEM). Finally, thermal analysis demonstrated that the thermal conductivity of the material was improved, maintaining the possibility of producing 3D printable formulations.

Thermal Conductivity Enhancement of Coaxial Carbon@Boron Nitride Nanotube Arrays

2017 ◽  
Vol 9 (17) ◽  
pp. 14555-14560 ◽  
Author(s):  
Lin Jing ◽  
Majid Kabiri Samani ◽  
Bo Liu ◽  
Hongling Li ◽  
Roland Yingjie Tay ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Boron Nitride ◽  
Thermal Conductivity Enhancement ◽  
Nanotube Arrays ◽  
Boron Nitride Nanotube ◽  
Conductivity Enhancement
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