Ultrasonic Study of Molecular Association of Polyethylenoxide Aqueous Solutions (A Method to Determine Molecular Weight)

1986 ◽  
Vol 18 (3) ◽  
pp. 187-190 ◽  
Author(s):  
Subhi Kemal Hassun ◽  
Suham H. F. Al-Madfai ◽  
Mustafa M. F. Al-Jarrah
Keyword(s):  
Molecular Weight ◽  
Aqueous Solutions ◽  
Molecular Association ◽  
Ultrasonic Study

scholarly journals An Ultrasonic Study of Sphere to Rod Transitions in Aqueous Solutions of Hexadecyltrimethylammonium Bromide.

1982 ◽  
Vol 36a ◽  
pp. 698-700 ◽  
Author(s):  
Sune Backlund ◽  
Harald Høiland ◽  
Ove J. Kvammen ◽  
Eva Ljosland ◽  
V. B. Sokolov ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Hexadecyltrimethylammonium Bromide ◽  
Ultrasonic Study

scholarly journals COMPLEXATION OF POLYETHYLENE-GLYCOL WITH THE SODIUM SALTS OF CITRIC AND SUCCINIC ACIDS IN THE AQUEOUS SOLUTIONS. STUDIES BY DYNAMIC LIGHT SCATTERING AND UV/VIS SPECTROPHOTOMETRY

2015 ◽  
Vol 11 (8) ◽  
pp. 3866-3872
Author(s):  
E.A. Masimov ◽  
Etibar Hummat Ismailov ◽  
S.Y. Odzhaqverdiyeva
Keyword(s):  
Molecular Weight ◽  
Light Scattering ◽  
Dynamic Light Scattering ◽  
Aqueous Solutions ◽  
Polyethylene Glycols ◽  
Hydrodynamic Diameter ◽  
Absorption Bands ◽  
Sodium Salts ◽  
And Diffusion ◽  
Formation Of Complexes

Dynamic light scattering (DLS) method in combination with the UV/VIS spectrophotometry is used to study the interaction of polyethylene- glycols with a molecular weight  6000 ( PEG6000 ) with sodium salts of citric and succinic acids in aqueous solutions. The values of density, viscosity, refractive and diffusion indexes, the values of the hydrodynamic diameter, wavelength electronic absorption bands for PEG6000 aqueous solutions, their mixtures with succinic and citric acids are determined. It was shown that depending on the composition of the solutions the values of hydrodynamic diameter for aqueous solutions containing 1-5 wt.% PEG6000 and their mixtures with succinic and citric acids (~ 1 wt%) ranges from 3.6 to 5.2 nm. It is assumed that the formation of complexes with the sizes  that are within the above range is due to the features of interaction  and the structure of the complexes formed in solution.

THE SORPTION OF SOAP BY TEXTILE FIBERS

1950 ◽  
Vol 28f (3) ◽  
pp. 51-61 ◽  
Author(s):  
A. S. Weatherburn ◽  
G. R. F. Rose ◽  
C. H. Bayley
Keyword(s):  
Molecular Weight ◽  
Fatty Acid ◽  
Aqueous Solutions ◽  
Sodium Oleate ◽  
Viscose Rayon ◽  
Free Alkali ◽  
Textile Fibers ◽  
Complex Process ◽  
Maximum Sorption ◽  
Preferential Sorption

The sorption of the sodium soaps of lauric, myristic, palmitic, stearic, and oleic acids from aqueous solutions by various textile fibers has been measured. The sorption of both the fatty acid and alkali components of the soaps by dull acetate rayon and dull nylon fibers was essentially the same as that shown by the corresponding bright (undelustered) fibers, while dull viscose rayon sorbed considerably more fatty acid than the bright fiber. In general, the order of increasing sorption was: cotton, nylon, acetate, bright viscose, dull viscose, and wool. Of the saturated soaps, the maximum sorption of fatty acid by all fibers was obtained with sodium myristate, while the alkali sorptions were approximately the same for myristate, palmitate, and stearate, all of which were higher than for laurate. The sorption from sodium oleate solutions corresponded approximately to that from the C14–C16 saturated soaps. Preferential sorption of alkali by cotton and viscose rayon was observed for all soaps, while acetate rayon, nylon, and wool showed preferential sorption of fatty acid with the lower molecular weight soaps and preferential sorption of alkali with the higher soaps. Suppression of hydrolysis by the addition of excess free alkali resulted in a reduction in fatty acid sorption in every case, and shifted the maximum from the C14 to the C16 soap. It is concluded that the sorption of soap by textile fibers is a complex process involving the more or less independent sorption of neutral soap, hydrolytic fatty acid (or acid soap), and hydrolytic alkali.

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