Electroinitiated emulsion polymerisation of vinyl monomers. III. Homopolymerisation and copolymerisation with vinyl acetate

1975 ◽  
Vol 7 (6) ◽  
pp. 429-433 ◽  
Author(s):  
Bryan M. Tidswell ◽  
Andrew W. Train
Keyword(s):  
Vinyl Acetate ◽  
Vinyl Monomers ◽  
Emulsion Polymerisation

Some aspects of the emulsion polymerisation of vinyl acetate

1975 ◽  
Vol 7 (3) ◽  
pp. 139-154 ◽  
Author(s):  
Vivian Stannett ◽  
Andrew Klein ◽  
Morton Litt
Keyword(s):  
Vinyl Acetate ◽  
Emulsion Polymerisation

The emulsion polymerisation of vinyl acetate by redox initiation

1973 ◽  
Vol 5 (4) ◽  
pp. 249-258 ◽  
Author(s):  
Brian G. Elgood ◽  
Edward V. Gulbekian
Keyword(s):  
Vinyl Acetate ◽  
Redox Initiation ◽  
Emulsion Polymerisation

Emulsion Polymerisation of Styrene and Vinyl Acetate

1970 ◽  
Vol 2 (1) ◽  
pp. 13-17 ◽  
Author(s):  
J. W. Breitenbach ◽  
K. Kuchner ◽  
H. Fritze ◽  
H. Tarnowiecki
Keyword(s):  
Vinyl Acetate ◽  
Emulsion Polymerisation

Pre-treatment of CaCO3 nanofiller by irradiation in the presence of vinyl monomers for the preparation of poly(vinyl acetate) composites

e-Polymers ◽  
2004 ◽  
Vol 4 (1) ◽  
Author(s):  
Mirela Leskovac ◽  
Vera Kovačević ◽  
Sanja Lučić Blagojević ◽  
Domagoj Vrsaljko ◽  
Vesna Volovšek
Keyword(s):  
Vinyl Acetate ◽  
Tensile Tests ◽  
Strong Interactions ◽  
Vinyl Monomers ◽  
Interfacial Interactions ◽  
Mechanical Mixing ◽  
Pre Treatment ◽  
Morphology And Mechanical Properties ◽  
Encapsulated Nanoparticles

AbstractPoly(vinyl acetate) (PVAc) composites were prepared by different approaches, namely (i) by mechanical mixing of untreated CaCO3 and PVAc, (ii) by mechanical mixing of CaCO3 pre-treated by irradiation polymerization in the presence of vinyl acetate, and (iii) by in situ emulsion polymerization of VAc in the presence of untreated CaCO3 nanofiller. The effects of nanoparticle pre-treatment and different approaches of preparation were correlated with changes in morphology and mechanical properties of PVAc composites using scanning electron microscopy and tensile tests. Untreated CaCO3 nanoparticles in the composite prepared by mechanical mixing provided strong interactions with the PVAc matrix. On the other hand, CaCO3 pre-treated nanoparticles decreased the interfacial interactions. For composites prepared by in situ polymerization a better dispersion of encapsulated nanoparticles was achieved and, as a result, a significant improvement of composite strength was observed. Interfacial interactions in nanocomposites can be changed by filler pre-treatment or by a suitable way of nanocomposite preparation.

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