Functionalized multiwalled carbon nanotubes as reinforcing agents for poly(vinyl alcohol) and poly(vinyl alcohol)/starch nanocomposites: synthesis, characterization and properties

2015 ◽  
Vol 64 (5) ◽  
pp. 689-695 ◽  
Author(s):  
Bakhshali Massoumi ◽  
Parivash Jafarpour ◽  
Mehdi Jaymand ◽  
Ali Akbar Entezami
Keyword(s):  
Carbon Nanotubes ◽  
Multiwalled Carbon Nanotubes ◽  
Vinyl Alcohol ◽  
Poly Vinyl Alcohol ◽  
Multiwalled Carbon ◽  
Functionalized Multiwalled Carbon Nanotubes

scholarly journals Effects of Polymer Matrices and Carbon Nanotubes on the Generation of Electric Energy in a Microbial Fuel Cell

2018 ◽  
Author(s):  
Yulia Plekhanova ◽  
Sergey Tarasov ◽  
Vladimir Kolesov ◽  
Iren Kuznetsova ◽  
Maria Signore ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Power Density ◽  
Multiwalled Carbon Nanotubes ◽  
Vinyl Alcohol ◽  
Electric Energy ◽  
Poly Vinyl Alcohol ◽  
Bacterial Cells ◽  
Multiwalled Carbon

The anode of a microbial fuel cell (MFC) was formed on a graphite electrode and immobilized Gluconobacter oxydans VKM-1280 bacterial cells. Immobilization was performed in chitosan, poly(vinyl alcohol) or N-vinylpyrrolidone-modified poly(vinyl alcohol). Ethanol was used as substrate. The anode was modified using multiwalled carbon nanotubes. The aim of the modification was to create a conductive network between cell lipid membranes, containing exposed PQQ-dependent alcoholdehydrogenases, and the electrode to facilitate electron transfer in the system. The bioelectrochemical characteristics of modified anodes at various cell/polymer ratios were assessed via current density, power density, polarization curves and impedance spectres. MFCs based on chitosan at a matrix/cell volume ratio of 5:1 produced maximal power characteristics of the system (8.3 μW/cm2) at a minimal resistance (1111 Ohm cm2). Modification of the anode by multiwalled carbon nanotubes led to a slight decrease of internal resistance (down to 1078 Ohm cm2) and to an increase of generated power density up to 10.6 μW/cm2. We explored the possibility of accumulating electric energy from an MFC on a 6,800-μF capacitor via a boost converter. Generated voltage was increased from 0.3 V up to 3.2 V. Accumulated energy was used to power a Clark-type biosensor and a bluetooth transmitter with three sensors, a miniature electric motor and a light-emitting diode.

scholarly journals Effects of Polymer Matrices and Carbon Nanotubes on the Generation of Electric Energy in a Microbial Fuel Cell

Membranes ◽  
2018 ◽  
Vol 8 (4) ◽  
pp. 99 ◽  
Author(s):  
Yulia Plekhanova ◽  
Sergei Tarasov ◽  
Vladimir Kolesov ◽  
Iren Kuznetsova ◽  
Maria Signore ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Power Density ◽  
Multiwalled Carbon Nanotubes ◽  
Microbial Fuel Cells ◽  
Vinyl Alcohol ◽  
Electric Energy ◽  
Poly Vinyl Alcohol ◽  
Multiwalled Carbon

The anode of a microbial fuel cell (MFC) was formed on a graphite electrode and immobilized Gluconobacter oxydans VKM-1280 bacterial cells. Immobilization was performed in chitosan, poly(vinyl alcohol) or N-vinylpyrrolidone-modified poly(vinyl alcohol). Ethanol was used as substrate. The anode was modified using multiwalled carbon nanotubes. The aim of the modification was to create a conductive network between cell lipid membranes, containing exposed pyrroloquinoline quinone (PQQ)-dependent alcoholdehydrogenases, and the electrode to facilitate electron transfer in the system. The bioelectrochemical characteristics of modified anodes at various cell/polymer ratios were assessed via current density, power density, polarization curves and impedance spectres. Microbial fuel cells based on chitosan at a matrix/cell volume ratio of 5:1 produced maximal power characteristics of the system (8.3 μW/cm2) at a minimal resistance (1111 Ohm cm2). Modification of the anode by multiwalled carbon nanotubes (MWCNT) led to a slight decrease of internal resistance (down to 1078 Ohm cm2) and to an increase of generated power density up to 10.6 μW/cm2. We explored the possibility of accumulating electric energy from an MFC on a 6800-μF capacitor via a boost converter. Generated voltage was increased from 0.3 V up to 3.2 V. Accumulated energy was used to power a Clark-type biosensor and a Bluetooth transmitter with three sensors, a miniature electric motor and a light-emitting diode.

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