Thermal properties and non-isothermal crystallization behavior of poly(trimethylene terephthalate)/poly(lactic acid) blends

2011 ◽  
pp. n/a-n/a ◽  
Author(s):  
Hantao Zou ◽  
Luoxin Wang ◽  
Changhai Yi ◽  
Houlei Gan
2017 ◽  
Vol 88 (14) ◽  
pp. 1616-1627 ◽  
Author(s):  
Shu-qiang Liu ◽  
Gai-hong Wu ◽  
Yun-chao Xiao ◽  
Hong-xia Guo ◽  
Fen-juan Shao

Poly(lactic acid) (PLA) fiber, owing to its biocompatibility and biodegradability, could be widely used in many related industrial areas. However, high brittleness has been the main obstacle to expanding its applications. So in this paper, carbon nanotube (CNT) nanocapsules were designed to toughen PLA and further reported their effect on the crystallization behavior and mechanical properties of PLA complex fiber. These designed CNT nanocapsules successfully solved the agglomeration of CNTs within the PLA matrix as well as the compatibility issue. In addition, the morphological, mechanical, optical and thermal properties of PLA complex fibers were also studied. The addition of CNT nanocapsules obviously improved the crystallization behavior of PLA fiber. Furthermore, compared with pure PLA, the tensile strength of PLA complex fiber was enhanced by 30.62% and the elongation by 32.2%, so the designed CNT nanocapsules could be used as a toughener for PLA fiber. This research benefits the extension of PLA applications where toughness is an important factor.


RSC Advances ◽  
2017 ◽  
Vol 7 (73) ◽  
pp. 46183-46194 ◽  
Author(s):  
Jia Yang ◽  
Hongwei Pan ◽  
Xin Li ◽  
Shulin Sun ◽  
Huiliang Zhang ◽  
...  

PPCU was prepared by using PPC and polyols as the raw materials and diphenyl-methane-diisocyanate (MDI) as the extender chain. The impact strength and elongation at break of PLA were remarkably enhanced by blending with PPCU.


2014 ◽  
Vol 887-888 ◽  
pp. 716-722
Author(s):  
Nai Xu ◽  
Xing Hui Wang ◽  
Li Sha Pan ◽  
Su Juan Pang ◽  
Xuan Chen ◽  
...  

The crystallization behavior and crystalline structure of poly (lactic acid) (PLA) filled with a novel nucleating agent (TMC328), which is a kind of aromatic amide derivatives, were investigated using differential scanning calorimetry (DSC) and wide angle X-ray (XRD). In isothermal crystallization from the melt, the present of TMC328 remarkably affected the isothermal crystalline behaviors of PLA. PLA/0.5% TMC328 sample exhibited very short crystallization half-times at 90-130 °C. Furthermore, the Avrami theory was used to describe the isothermal crystallization kinetics of PLA/TMC328 samples. It is confirmed that TMC328 showed a significant heterogeneous nucleation effect on the crystallization of PLA matrix. Moreover, XRD measurement indicates that TMC328 is a kind of α-form nucleating agent for PLA.


2009 ◽  
Vol 30 (9) ◽  
pp. 1338-1344 ◽  
Author(s):  
Xiaoxiu Li ◽  
Jingbo Yin ◽  
Zhenyang Yu ◽  
Shifeng Yan ◽  
Xiaochun Lu ◽  
...  

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