Variation of non-isothermal crystallization behavior of isotactic polypropylene with varying β-nucleating agent content

2010 ◽  
Vol 59 (10) ◽  
pp. 1441-1450 ◽  
Author(s):  
Linli Xu ◽  
Xiuju Zhang ◽  
Kai Xu ◽  
Shaoquan Lin ◽  
Mingcai Chen
Keyword(s):  
Isotactic Polypropylene ◽  
Isothermal Crystallization ◽  
Crystallization Behavior ◽  
Nucleating Agent

Isothermal Crystallization Behavior of Poly (L-lactic Acid)/ Surface-Grafted Silica Nanocomposites

2012 ◽  
Vol 268-270 ◽  
pp. 37-40 ◽  
Author(s):  
Yan Hua Cai
Keyword(s):  
Lactic Acid ◽  
Isothermal Crystallization ◽  
Crystallization Behavior ◽  
Nucleating Agent ◽  
Melt Blending ◽  
Scanning Calorimetry ◽  
Silica Nanocomposites ◽  
Induction Periods ◽  
Sio2 Nanocomposites ◽  
Different Content

The Poly(L-lactic acid)(PLLA)/surface-grafting silica(g-SiO2) nanocomposites were prepared by melt blending. The isothermal crystallization behavior of PLLA/g-SiO2 nanocomposites with different content of g-SiO2 was investigated by optical depolarizer. In isothermal crystallization from melt, the induction periods and half times for overall PLLA crystallization (95°C Tc 120°C) were affected by the crystallization temperature and the content of g-SiO2 in nanocomposites. The results showed that g-SiO2 as a kind of heterogeneous nucleating agent can reduce induction periods and half times for overall PLLA crystallization. The thermal properties of PLLA/g-SiO2 samples were also investigated by differential scanning calorimetry (DSC), The results showed that the crystalline degree of PLLA was improved as the presence of g-SiO2.

Influence of Shear on Crystallization Behavior of theβPhase in Isotactic Polypropylene withβ-Nucleating Agent

2004 ◽  
Vol 37 (7) ◽  
pp. 2478-2483 ◽  
Author(s):  
Hong Huo ◽  
Shichun Jiang ◽  
Lijia An ◽  
Jiachun Feng
Keyword(s):  
Isotactic Polypropylene ◽  
Crystallization Behavior ◽  
Nucleating Agent

Crystallization behavior of isotactic polypropylene induced by competition action of β nucleating agent and high pressure

2011 ◽  
Vol 290 (6) ◽  
pp. 531-540 ◽  
Author(s):  
Gang Yang ◽  
Xiaoxi Li ◽  
Jingwei Chen ◽  
Jinghui Yang ◽  
Ting Huang ◽  
...  
Keyword(s):  
High Pressure ◽  
Isotactic Polypropylene ◽  
Crystallization Behavior ◽  
Nucleating Agent

Isothermal and non-isothermal crystallization of isotactic polypropylene in the presence of an α nucleating agent and zeolite 13X

2018 ◽  
Vol 667 ◽  
pp. 9-18 ◽  
Author(s):  
Xin Meng ◽  
Weiguang Gong ◽  
Weijie Chen ◽  
Yaoqi Shi ◽  
Yan Sheng ◽  
...  
Keyword(s):  
Isotactic Polypropylene ◽  
Isothermal Crystallization ◽  
Nucleating Agent ◽  
Zeolite 13X

scholarly journals Study on non-isothermal crystallization behavior of isotactic polypropylene/bacterial cellulose composites

RSC Advances ◽  
2017 ◽  
Vol 7 (67) ◽  
pp. 42113-42122 ◽  
Author(s):  
Bo Wang ◽  
Hai-Rong Zhang ◽  
Chao Huang ◽  
Lian Xiong ◽  
Jun Luo ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Bacterial Cellulose ◽  
Isotactic Polypropylene ◽  
Isothermal Crystallization ◽  
Crystallization Behavior ◽  
High Crystallinity ◽  
Cellulose Composites

Bacterial cellulose (BC) has great potential to be used as a new filler in reinforced isotactic polypropylene (iPP) due to its characteristics of high crystallinity, biodegradability and efficient mechanical properties.

Thermal behavior of modified poly(L-lactic acid): effect of aromatic multiamide derivative based on 1H-benzotriazole

e-Polymers ◽  
2016 ◽  
Vol 16 (4) ◽  
pp. 303-311 ◽  
Author(s):  
Yan-Hua Cai ◽  
Li-Sha Zhao
Keyword(s):  
Thermal Stability ◽  
Thermal Decomposition ◽  
Lactic Acid ◽  
Isothermal Crystallization ◽  
Crystallization Behavior ◽  
Nucleating Agent ◽  
Melting Behavior ◽  
Decomposition Temperature ◽  
Scanning Calorimetry ◽  
Onset Crystallization Temperature

AbstractThe goal of this work was to synthesis a novel aromatic multiamide derivative based on 1H-benzotriazole (PB) as an organic nucleating agent for poly(L-lactic acid) (PLLA), and investigate the effect of PB on the non-isothermal crystallization, melting behavior and thermal decomposition of PLLA. Here, PB was firstly synthesized through 1H-benzotriazole aceto-hydrazide and terephthaloyl chloride, then PB-nucleated PLLA was fabricated via melt-blending technology at various PB concentration from 0.5 wt% to 3 wt%. Finally, the thermal performances were evaluated through differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The high thermal decomposition temperature of PB indicated that PB possessed possibility as a nucleating agent for PLLA, and the non-isothermal crystallization behavior confirmed the crystallization accelerating effectiveness of PB for PLLA. Upon optimum concentration of 2 wt%, the onset crystallization temperature, the crystallization peak temperature and the non-isothermal crystallization enthalpy increased from 101.4°C, 94.5°C and 0.1 J·g-1 to 121.3°C, 115.8°C and 35.1 J·g-1, respectively. In addition, the non-isothermal crystallization behavior was also affected by the cooling rate and the final melting temperature. The melting behavior further evidenced the advanced nucleating ability of PB, and the competitive relationship between PB and the heating rate, the nuclear rate and crystal growth rate. Thermal stability measurement showed that PB with a concentration of 1 wt%–2 wt% could slightly improve the thermal stability of PLLA.

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