Biodegradable poly(ester-ether)s: ring-opening polymerization of D,L-3-methyl-1,4-dioxan-2-one using various initiator systems

2010 ◽  
Vol 59 (9) ◽  
pp. 1310-1318 ◽  
Author(s):  
Yemanlall Lochee ◽  
Dhanjay Jhurry ◽  
Archana Bhaw-Luximon ◽  
Afksendiyos Kalangos
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Biodegradable Poly

Synthesis of Biodegradable Poly-ε-caprolactone Microspheres by Dispersion Ring-Opening Polymerization in Supercritical Carbon Dioxide

2008 ◽  
Vol 9 (11) ◽  
pp. 3141-3149 ◽  
Author(s):  
Bruno Grignard ◽  
Fabrice Stassin ◽  
Cédric Calberg ◽  
Robert Jérôme ◽  
Christine Jérôme
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Biodegradable Poly ◽  
Supercritical Carbon

scholarly journals From Anionic Ring-Opening Polymerization of β-Butyrolactone to Biodegradable Poly(hydroxyalkanoate)s: Our Contributions in This Field

Polymers ◽  
2021 ◽  
Vol 13 (24) ◽  
pp. 4365
Author(s):  
Grażyna Adamus ◽  
Adrian Domiński ◽  
Marek Kowalczuk ◽  
Piotr Kurcok ◽  
Iza Radecka
Keyword(s):  
Ring Opening ◽  
Polymeric Materials ◽  
Ring Opening Polymerization ◽  
Random Copolymers ◽  
Acid Analogue ◽  
Biodegradable Poly ◽  
Anionic Ring ◽  
Synthetic Approaches ◽  
Hydroxybutanoic Acid ◽  
The Relationship

The feasibility of synthesis of functionalized poly(3-hydroxybutanoic acid) analogue and its copolymers via ring-opening polymerization of β-butyrolactone mediated by activated anionic initiators is presented. Using these new synthetic approaches, polyesters with a defined chemical structure of the end groups, as well as block, graft, and random copolymers, have been obtained and characterized by modern instrumental techniques, with special emphasis on ESI-MS. The relationship between the structure and properties of the prepared polymeric materials is also discussed.

Synthesis and rheology of biodegradable poly(glycolic acid) prepared by melt ring-opening polymerization of glycolide

2009 ◽  
Vol 47 (5) ◽  
pp. 1440-1449 ◽  
Author(s):  
Estelle Gautier ◽  
Patrick Fuertes ◽  
Philippe Cassagnau ◽  
Jean-Pierre Pascault ◽  
Etienne Fleury
Keyword(s):  
Ring Opening ◽  
Glycolic Acid ◽  
Ring Opening Polymerization ◽  
Biodegradable Poly

A Recommender System for Inverse Design of Polycarbonates and Polyesters

2020 ◽  
Author(s):  
Nathaniel Park ◽  
Dmitry Yu. Zubarev ◽  
James L. Hedrick ◽  
Vivien Kiyek ◽  
Christiaan Corbet ◽  
...  
Keyword(s):  
Ring Opening ◽  
High Performance ◽  
Recommendation System ◽  
Polymeric Materials ◽  
Monomer Conversion ◽  
Design Strategy ◽  
Ring Opening Polymerization ◽  
Inverse Design ◽  
False Negatives ◽  
Accelerate Development

The convergence of artificial intelligence and machine learning with material science holds significant promise to rapidly accelerate development timelines of new high-performance polymeric materials. Within this context, we report an inverse design strategy for polycarbonate and polyester discovery based on a recommendation system that proposes polymerization experiments that are likely to produce materials with targeted properties. Following recommendations of the system driven by the historical ring-opening polymerization results, we carried out experiments targeting specific ranges of monomer conversion and dispersity of the polymers obtained from cyclic lactones and carbonates. The results of the experiments were in close agreement with the recommendation targets with few false negatives or positives obtained for each class.<br>

Bisurea and Bisthiourea H-Bonding Organocatalysts for Ring-Opening Polymerization: Cues for the Catalyst Design

2019 ◽  
Vol 52 (23) ◽  
pp. 9232-9237 ◽  
Author(s):  
Rukshika S. Hewawasam ◽  
U. L. D. Inush Kalana ◽  
Nayanthara U. Dharmaratne ◽  
Thomas J. Wright ◽  
Timothy J. Bannin ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Catalyst Design
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