Influence of ammonium polyphosphate on the flame retardancy and mechanical properties of ramie fiber-reinforced poly(lactic acid) biocomposites

2009 ◽  
Vol 59 (2) ◽  
pp. 242-248 ◽  
Author(s):  
Li Shumao ◽  
Ren Jie ◽  
Yuan Hua ◽  
Yu Tao ◽  
Yuan Weizhong
2019 ◽  
pp. 089270571986461
Author(s):  
Kubra Coskun ◽  
Aysenur Mutlu ◽  
Mehmet Dogan ◽  
Ebru Bozacı

The effects of enzymatic treatments on the properties of coir fiber-reinforced poly(lactic acid) (PLA) were not found in the literature. Accordingly, the effects of various enzymatic treatments on the mechanical performance of the coir fiber-reinforced PLA composites were investigated in the current study. Four different enzymes, namely lipase, lactase, pectinase, and cellulase, were used. The mechanical properties of the composites were determined by the tensile, flexural, impact tests, and dynamic mechanical analysis. According to the test results, the use of enzyme treated coir fibers affected the mechanical properties except for the flexural properties with different extents depending upon their type. The tensile strength increased with the treatments of lipase and lactase, while the treatments with pectinase and cellulase had no remarkable effect. The impact strength was improved with enzymatic treatments except for pectinase. All enzymatic treatments improved the elastic modulus below the glass transition temperature. In brief, enzymatic treatments improved the interfacial adhesion between coir fiber and PLA via the waxes and fatty acids removal and/or the increment in surface roughness.


2019 ◽  
Vol 19 (11) ◽  
pp. 7074-7082 ◽  
Author(s):  
Tao Yu ◽  
Changqing Hu ◽  
Yan Li

In this work, 9,10-dihydro-9-oxa-phosphaphenanthrene-10-oxide (DOPO) was covalently grafted onto the surface of graphene to get modified graphene (G-DOPO) firstly. The mechanical properties and flame retardancy of jute/poly(lactic acid) (PLA) composite with G-DOPO were studied. According to Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS), it was confirmed that DOPO was grafted on the surface of graphene successfully. Thermogravimetric analysis (TGA) results demonstrated that the residue char of the composites increased with the addition of G-DOPO. The total heat release (THR) of the composite was significantly reduced and the limiting oxygen index (LOI) increased after adding G-DOPO into the composite. Moreover, the mechanical properties results showed that the comprehensive effects of G-DOPO on the interface enhancement and matrix toughness were found.


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