Plasma treatment-induced fluorine-functionalized multi-walled carbon nanotubes to modify poly(ethylene terephthalate) obtained via in situ polymerization

2009 ◽  
Vol 59 (2) ◽  
pp. 198-203
Author(s):  
Ping Luo ◽  
Kun Jiang ◽  
Ke Wang ◽  
Jinghui Yang ◽  
Tao Xu ◽  
...  
2010 ◽  
Vol 150-151 ◽  
pp. 1017-1021
Author(s):  
Ruo Xi Wang ◽  
Hua Wang ◽  
Xing You Tian ◽  
Qing Yan ◽  
Kang Zheng ◽  
...  

Antistatic Poly(ethylene terephthalate) (PET) materials had been successfully prepared through solution-blending incorporation of ethylene glycol-graft-Multi-walled carbon nanotubes (EG-g-MWCNTs). MWCNTs were first carboxylated and then esterified with EG to yield EG-g-MWCNTs. The FT-IR spectra, TEM images, Raman spectra, TGA curves and electrical conductivity were investigated, which indicated that the agglomeration degree of MWCNTs has been reduced and the conductivity keeps as high as 4.278 S/cm after the modification of EG. On the other hand, EG-g-MWCNTs dispersed well in EG, which was one of the synthetic monomers for PET, and thus ensured its good compatibility with PET. As a result, the electrical conductivity of PET/EG-g-MWCNTs nanocomposites (0.1 wt%) was seven orders of magnitude higher than pure PET and reached the antistatic level.


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