Synthesis and characterization of new optically active polymers carrying calix[4]arene and amino acid units in the main chain and their binding properties towards toxic heavy metals

2009 ◽  
Vol 58 (6) ◽  
pp. 630-639 ◽  
Author(s):  
Abdol-Reza Hajipour ◽  
Sakineh Habibi ◽  
Arnold E Ruoho
Keyword(s):  
Heavy Metals ◽  
Amino Acid ◽  
Main Chain ◽  
Optically Active ◽  
Synthesis And Characterization ◽  
Optically Active Polymers ◽  
Toxic Heavy Metals ◽  
Binding Properties

Synthesis of A 1,1′-Binaphthyl Based Main Chain Chiral Conjugated Polymer

1995 ◽  
Vol 413 ◽  
Author(s):  
Qiao-Sheng Hu ◽  
Dilrukshi Vitharana ◽  
Lin Pu
Keyword(s):  
Absorption Spectrum ◽  
Boronic Acid ◽  
Conjugated Polymer ◽  
Main Chain ◽  
Repeat Unit ◽  
Suzuki Coupling ◽  
Optically Active ◽  
Synthesis And Characterization ◽  
Palladium Catalyzed

ABSTRACTThe synthesis and characterization of a 1,1′-binaphthyl based main chain chiral conjugated polymer, R-9, is described. The polymer is prepared from the palladium-catalyzed Suzuki coupling of an optically active binaphthyl molecule, (R)-2,2′-dihexyloxy-1,1′-binaphthyl-6,6′- diboronic acid, R-4 with 1,4-bis(p-bromostyryl)benzene (E:Z = 1:1.2), 8. The Suzuki coupling of 8 with 6-neopentyloxynaphthyl-2-boronic acid, 1 1, leads to the formation of a conjugated molecule 10. The structure of this molecule represents the repeat unit of R-9. The electronic absorption spectrum of 10 demonstrates that the degree of conjugation in the chiral conjugated polymer is almost the same as that of its repeat unit.

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