Isothermal crystallization kinetics of silk fibroin fiber-reinforced poly(ε-caprolactone) biocomposites

2009 ◽  
Vol 58 (5) ◽  
pp. 530-537 ◽  
Author(s):  
Xiuying Qiao ◽  
Wei Li ◽  
Kang Sun ◽  
Shi Xu ◽  
Xiaodong Chen
Keyword(s):  
Silk Fibroin ◽  
Crystallization Kinetics ◽  
Isothermal Crystallization ◽  
Fiber Reinforced ◽  
Isothermal Crystallization Kinetics ◽  
Silk Fibroin Fiber ◽  
Kinetics Of

scholarly journals Non-isothermal crystallization kinetics of ramie fiber-reinforced polylactic acid biocomposite

RSC Advances ◽  
2017 ◽  
Vol 7 (73) ◽  
pp. 46014-46021 ◽  
Author(s):  
Xing Jin ◽  
Xie Chen ◽  
Qian Cheng ◽  
Naiwen Zhang ◽  
Shenyang Cai ◽  
...  
Keyword(s):  
Polylactic Acid ◽  
Crystallization Kinetics ◽  
Isothermal Crystallization ◽  
Energy Barrier ◽  
Ramie Fiber ◽  
Fiber Reinforced ◽  
Isothermal Crystallization Kinetics ◽  
Kinetics Of

The addition of RF weakened the interaction between PLA chains and reduced the energy barrier of PLA during crystallization.

scholarly journals Isothermal Crystallization Kinetics of Poly(ethylene oxide)/Poly(ethylene glycol)-g-silica Nanocomposites

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 648
Author(s):  
Xiangning Wen ◽  
Yunlan Su ◽  
Shaofan Li ◽  
Weilong Ju ◽  
Dujin Wang
Keyword(s):  
Molecular Weight ◽  
Ethylene Oxide ◽  
Crystallization Kinetics ◽  
Isothermal Crystallization ◽  
Crystallization Rate ◽  
Poly Ethylene Glycol ◽  
Isothermal Crystallization Kinetics ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene ◽  
Kinetics Of

In this work, the crystallization kinetics of poly(ethylene oxide) (PEO) matrix included with poly(ethylene glycol) (PEG) grafted silica (PEG-g-SiO2) nanoparticles and bare SiO2 were systematically investigated by differential scanning calorimetry (DSC) and polarized light optical microscopy (PLOM) method. PEG-g-SiO2 can significantly increase the crystallinity and crystallization temperature of PEO matrix under the non-isothermal crystallization process. Pronounced effects of PEG-g-SiO2 on the crystalline morphology and crystallization rate of PEO were further characterized by employing spherulitic morphological observation and isothermal crystallization kinetics analysis. In contrast to the bare SiO2, PEG-g-SiO2 can be well dispersed in PEO matrix at low P/N (P: Molecular weight of matrix chains, N: Molecular weight of grafted chains), which is a key factor to enhance the primary nucleation rate. In particular, we found that the addition of PEG-g-SiO2 slows the spherulitic growth fronts compared to the neat PEO. It is speculated that the interfacial structure of the grafted PEG plays a key role in the formation of nuclei sites, thus ultimately determines the crystallization behavior of PEO PNCs and enhances the overall crystallization rate of the PEO nanocomposites.

Non-isothermal Crystallization Kinetics of Mold Fluxes for Casting High-Aluminum Steels

2017 ◽  
Vol 48 (6) ◽  
pp. 2949-2960 ◽  
Author(s):  
Lejun Zhou ◽  
Huan Li ◽  
Wanlin Wang ◽  
Zhaoyang Wu ◽  
Jie Yu ◽  
...  
Keyword(s):  
Crystallization Kinetics ◽  
Isothermal Crystallization ◽  
Isothermal Crystallization Kinetics ◽  
Mold Fluxes ◽  
Kinetics Of ◽  
High Aluminum
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