Synthesis and properties of novel aromatic poly(ester-amide)s derived from 1,5-bis(3-aminobenzoyloxy)naphthalene and aromatic dicarboxylic acids

2004 ◽  
Vol 54 (2) ◽  
pp. 392-400 ◽  
Author(s):  
Sheng-Huei Hsiao ◽  
Wen-Tsuen Leu
2020 ◽  
Vol 32 (9) ◽  
pp. 1001-1009
Author(s):  
Yi-Sheng Luo ◽  
Qiu-Ying Wang ◽  
Xue-Chun Mao ◽  
Shou-Ri Sheng

A new aromatic diamine, 10,10-bis[4-(4-aminophenoxy)phenyl]-9(10 H)-anthrone (BAPA) has been synthesized from anthrone via three-step procedure. Direct phosphorylation polycondensation of BAPA with various aromatic dicarboxylic acids produced a series of cardo poly(ether amide)s with inherent viscosities of 0.97–1.29 dL g−1. All the polymers were readily soluble in polar solvents such as N-methyl-2-pyrrolidone, N, N-dimethylacetamide (DMAc), and pyridine at room temperature, and afforded transparent, strong, and flexible films upon casting from DMAc solvent. The resulting poly(ether amide)s had glass transition temperatures of 254–316°C, 10% weight loss temperatures of 495–524°C, and char yields of 55–70% at 800°C in nitrogen. These polymers were amorphous and their films exhibited tensile strengths of 81.6–104.7 MPa, tensile moduli of 1.8–2.4 GPa, and elongations at break of 8–15%.


1989 ◽  
Vol 21 (8) ◽  
pp. 661-664
Author(s):  
Yoshiyuki Oishi ◽  
Shoichi Nakata ◽  
Mikio Kajiyama ◽  
Masa-aki Kakimoto ◽  
Yoshio Imai

1972 ◽  
Vol 126 (3) ◽  
pp. 20P-21P ◽  
Author(s):  
H Harris ◽  
T Kalogerakos ◽  
A E Evangelopoulos ◽  
P M Bayley

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