Ultra-high-modulus linear polyethylene through controlled molecular weight and drawing

1975 ◽  
Vol 15 (3) ◽  
pp. 219-224 ◽  
Author(s):  
G. Capaccio ◽  
I. M. Ward
2015 ◽  
Vol 594 ◽  
pp. 012010 ◽  
Author(s):  
Yu V Zavgorodnev ◽  
S N Chvalun ◽  
G Yu Nikolaeva ◽  
E A Sagitova ◽  
P P Pashinin ◽  
...  

2021 ◽  
Vol 2103 (1) ◽  
pp. 012095
Author(s):  
L P Myasnikova ◽  
A K Borisov ◽  
Yu M Boiko ◽  
A P Borsenko ◽  
V F Drobot’ko ◽  
...  

Abstract The ultra-high-molecular-weight polyethylene reactor powders are widely used for the actively developing solvent-free method for producing high-strength high-modulus PE filaments, which includes the compaction and sintering of a powder followed by orientational hardening. To find an appropriate regime of the technological process, it is important to know how the nanostructure changes when transforming from a powder to a precursor for hardening. Nanocrystalline lamellae are characteristics of the powder structure. For the first time, the DSC technique was used to follow changes in the thickness distribution of lamellae in ultra-high-molecular-weight polyethylene reactor powder on its way to a precursor for orientation hardening. It was found that the percentage of thick (>15 nm) and thin (10 nm) lamellae in compacted samples and those sintered at temperatures lower than the melting temperature of PE (140°C) remains nearly the same. However, significant changes in the content of lamellae of different thicknesses were observed in the samples sintered at 145°C with subsequent cooling under different conditions. The influence of the lamellae thickness distribution in precursors on the mechanical characteristics of oriented filaments was discussed.


Polymer ◽  
1982 ◽  
Vol 23 (6) ◽  
pp. 935-936 ◽  
Author(s):  
J Clements ◽  
I.M Ward

2011 ◽  
Vol 287-290 ◽  
pp. 1155-1163
Author(s):  
Shao Long Huang ◽  
Fan Shen ◽  
Qing Jun Ding

In this paper, recycled PE was added directly to the asphalt mixture to prepare high modulus asphalt mixture. To study the influence of the dosage and molecular weight of recycled PE on the performance of asphalt mixture, three kinds of recycled PE with different molecular weight and three asphalt binders (Conventional, SBS Modified and PE Modified) were used to prepare eight kinds of asphalt mixture. Various tests, including dynamic modulus, wheel tracking and Lottman test, were conducted to evaluate the performance of them. The results showed that 1) the dynamic modulus of asphalt mixture modified by recycled PE is higher than the normal mixture and mixture prepared with SBS modified asphalt binder; 2) adding recycled PE directly into the asphalt mixture during mixing is more effective than preparing asphalt mixture with PE modified asphalt binder in making high modulus asphalt mixture; 3) the recycled PE used to produce high modulus asphalt mixture should have certain big molecular weight, more than 27,000, and the dosage of recycled PE should be no less than 0.4% of the total weight of asphalt mixture. The performance tests indicted the good high temperature deformation resistance property of asphalt mixture modified by recycled PE.


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