Relationships between impact performance and structures of rotationally molded crosslinked high‐density polyethylene

Author(s):  
Yueqing Ren ◽  
Xiaojie Sun ◽  
Yafei Li ◽  
Lanlan Chen ◽  
Miaomiao Sun ◽  
...  
Author(s):  
Wijang Wisnu Raharjo ◽  
Bambang Kusharjanto ◽  
Teguh Triyono

In this study, an environmentally friendly composite was prepared from cantala fiber and recycled high-density polyethylene. Alkali treatment was utilized to improve the fiber–matrix interface of cantala fiber. The alkali treatment was carried out with a 2% NaOH solution for periods of 0, 4, 8, 12, 16, 20, and 24 hours. Various recycled high-density polyethylene composites reinforced with treated and untreated short cantala fiber were produced by hot press. The tensile and impact properties of the composites were examined to reveal the effect of alkali treatment. Changes in fiber–matrix bonding were investigated via composite fractography using scanning electron microscopy. A study of fiber morphology and other supporting tests, such as the fiber tensile test, X-ray diffraction, and Fourier transform infrared microscopy were also carried out. The results show that the addition of alkali-treated fiber to recycled high-density polyethylene composites enhanced the composites’ tensile and impact performance: Tensile strength improved by 15.5% and impact strength by 24.8%.


2003 ◽  
Vol 774 ◽  
Author(s):  
Susan M. Rea ◽  
Serena M. Best ◽  
William Bonfield

AbstractHAPEXTM (40 vol% hydroxyapatite in a high-density polyethylene matrix) and AWPEX (40 vol% apatite-wollastonite glass ceramic in a high density polyethylene matrix) are composites designed to provide bioactivity and to match the mechanical properties of human cortical bone. HAPEXTM has had clinical success in middle ear and orbital implants, and there is great potential for further orthopaedic applications of these materials. However, more detailed in vitro investigations must be performed to better understand the biological interactions of the composites and so the bioactivity of each material was assessed in this study. Specifically, the effects of controlled surface topography and ceramic filler composition on apatite layer formation in acellular simulated body fluid (SBF) with ion concentration similar to those of human blood plasma were examined. Samples were prepared as 1 cm × 1 cm × 1 mm tiles with polished, roughened, or parallel-grooved surface finishes, and were incubated in 20 ml of SBF at 36.5 °C for 1, 3, 7, or 14 days. The formation of a biologically active apatite layer on the composite surface after immersion was demonstrated by thin-film x-ray diffraction (TF-XRD), environmental scanning electron microscopy (ESEM) imaging and energy dispersive x-ray (EDX) analysis. Variations in sample weight and solution pH over the period of incubation were also recorded. Significant differences were found between the two materials tested, with greater bioactivity in AWPEX than HAPEXTM overall. Results also indicate that within each material the surface topography is highly important, with rougher samples correlated to earlier apatite formation.


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