Double yielding behavior of in situ microfibrillar polyolefin elastomer/poly(lactic acid) composites: Effect of microfibrillar morphology

2020 ◽  
Vol 60 (7) ◽  
pp. 1676-1685
Author(s):  
Jing Sun ◽  
Shanshan Luo ◽  
Anrong Huang ◽  
Min Shi ◽  
Heng Luo ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Poly Lactic Acid ◽  
Polyolefin Elastomer ◽  
Yielding Behavior

Super‐tough poly(lactic acid) using a fully bio‐based polyester containing malic acid via in‐situ interfacial compatibilization

2021 ◽  
pp. 51413
Author(s):  
Rong Yang ◽  
Hongwei Cao ◽  
Chong Li ◽  
Guoxiang Zou ◽  
Xin Zhang ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Malic Acid ◽  
Poly Lactic Acid

scholarly journals Morphology, Thermal, Mechanical Properties and Rheological Behavior of Biodegradable Poly(butylene succinate)/poly(lactic acid) In-Situ Submicrofibrillar Composites

Materials ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 2422 ◽  
Author(s):  
Zhiwen Zhu ◽  
Hezhi He ◽  
Bin Xue ◽  
Zhiming Zhan ◽  
Guozhen Wang ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Cold Drawing ◽  
Mechanical Analysis ◽  
Poly Lactic Acid ◽  
Fiber Morphology ◽  
Molding Process ◽  
Butylene Succinate ◽  
Low Frequencies ◽  
Biodegradable Poly

In this study, biodegradable poly(butylene succinate)/poly(lactic acid) (PBS/PLA) in-situ submicrofibrillar composites with various PLA content were successfully produced by a triple-screw extruder followed by a hot stretching−cold drawing−compression molding process. This study aimed to investigate the effects of dispersed PLA submicro-fibrils on the thermal, mechanical and rheological properties of PBS/PLA composites. Morphological observations demonstrated that the PLA phases are fibrillated to submicro-fibrils in the PBS/PLA composites, and all the PLA submicro-fibrils produced seem to have a uniform diameter of about 200nm. As rheological measurements revealed, at low frequencies, the storage modulus (G’) of PBS/PLA composites has been increased by more than four orders of magnitude with the inclusion of high concentrations (15 wt % and 20 wt %) of PLA submicro-fibrils, which indicates a significant improvement in the elastic responses of PBS melt. Dynamic Mechanical Analysis (DMA) results showed that the glass transition temperature (Tg) of PBS phase slightly shifted to the higher temperature after the inclusion of PLA. DSC experiments proved that fiber morphology of PLA has obvious heterogeneous nucleation effect on the crystallization of PBS. The tensile properties of the PBS/PLA in-situ submicrofibrillar composites are also improved compared to neat PBS.

Rheological rationalization of in situ nanofibrillar structure development: Tailoring of nanohybrid shish-kebab superstructures of poly (lactic acid) crystalline phase

Polymer ◽  
2020 ◽  
Vol 211 ◽  
pp. 123040
Author(s):  
Mahboobeh Shahnooshi ◽  
Azizeh Javadi ◽  
Hossein Nazockdast ◽  
Katharina Ottermann ◽  
Volker Altstädt
Keyword(s):  
Lactic Acid ◽  
Crystalline Phase ◽  
Poly Lactic Acid ◽  
Structure Development

Unprecedented Access to Strong and Ductile Poly(lactic acid) by Introducing In Situ Nanofibrillar Poly(butylene succinate) for Green Packaging

2014 ◽  
Vol 15 (11) ◽  
pp. 4054-4064 ◽  
Author(s):  
Lan Xie ◽  
Huan Xu ◽  
Ben Niu ◽  
Xu Ji ◽  
Jun Chen ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Poly Lactic Acid ◽  
Butylene Succinate ◽  
Green Packaging
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