Influence of carbon black properties on the Joule heating stimulated shape-memory behavior of filledethylene-1-octene copolymer

2010 ◽  
Vol 51 (3) ◽  
pp. 500-508 ◽  
Author(s):  
Hai Hong Le ◽  
Osayuki Osazuwa ◽  
Igor Kolesov ◽  
Sybill Ilisch ◽  
Hans-Joachim Radusch
Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 807 ◽  
Author(s):  
Lin Xia ◽  
Han Gao ◽  
Weina Bi ◽  
Wenxin Fu ◽  
Guixue Qiu ◽  
...  

Shape memory composites of trans-1,4-polyisoprene (TPI) and low-density polyethylene (LDPE) with easily achievable transition temperatures were prepared by a simple physical blending method. Carbon black (CB) was introduced to improve the mechanical properties of the TPI/LDPE composites. The mechanical, cure, thermal and shape memory properties of the TPI/LDPE/CB composites were investigated in this study. In these composites, the crosslinked network generated in both the TPI and LDPE portions acted as a fixed domain, while the crystalline regions of the TPI and LDPE portions acted as a reversible domain in shape memory behavior. We found the mechanical properties of composites were promoted significantly with an increase of CB content, accompanied with the deterioration of shape memory properties of composites. When CB dosage was 5 parts per hundred of rubber composites (phr), best shape memory property of composites was obtained with a shape fixity ratio of 95.1% and a shape recovery ratio of 95.0%.


Author(s):  
Eva Sanchez-Rexach ◽  
Patrick T. Smith ◽  
Alvaro Gomez-Lopez ◽  
Maxence Fernandez ◽  
Aitziber L. Cortajarena ◽  
...  

2020 ◽  
Vol 8 (24) ◽  
pp. 9125-9135 ◽  
Author(s):  
Fiona Magliozzi ◽  
Arthur Scali ◽  
Guillaume Chollet ◽  
Damien Montarnal ◽  
Etienne Grau ◽  
...  

2008 ◽  
Vol 47-50 ◽  
pp. 714-717 ◽  
Author(s):  
Xin Lan ◽  
Jin Song Leng ◽  
Yan Ju Liu ◽  
Shan Yi Du

A new system of thermoset styrene-based shape-memory polymer (SMP) filled with carbon black (CB) is investigated. To realize the electroactive stimuli of SMP, the electrical conductivity of SMP filled with various amounts of CB is characterized. The percolation threshold of electrically conductive SMP filled with CB is about 3% (volume fraction of CB), which is much lower than many other electrically conductive polymers. When applying a voltage of 30V, the shape recovery process of SMP/CB(10 vol%) can be realized in about 100s. In addition, the thermomechanical properties are also characterized by differential scanning calorimetery (DSC).


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