Rheokinetics of ring-opening metathesis polymerization of norbornene-based monomers intended for self-healing applications

2006 ◽  
Vol 46 (12) ◽  
pp. 1804-1811 ◽  
Author(s):  
G. E. Larin ◽  
N. Bernklau ◽  
M. R. Kessler ◽  
J. C. DiCesare
Keyword(s):  
Ring Opening ◽  
Self Healing ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization

scholarly journals Reversible Assembly of Terpyridine Incorporated Norbornene-Based Polymer via a Ring-Opening Metathesis Polymerization and Its Self-Healing Property

Polymers ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1173 ◽  
Author(s):  
Jookyeong Lee ◽  
Hwi Moon ◽  
Keewook Paeng ◽  
Changsik Song
Keyword(s):  
Ring Opening ◽  
Transition Metal Ions ◽  
Self Healing ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization ◽  
Ligand Interactions ◽  
Healing Agent ◽  
Healing Property ◽  
External Stimuli ◽  
Metal Ligand

We induced a terpyridine moiety into a norbornene-based polymer to demonstrate its self-healing property, without an external stimulus, such as light, heat, or healing agent, using metal–ligand interactions. We synthesized terpyridine incorporated norbornene-based polymers using a ring-opening metathesis polymerization. The sol state of diluted polymer solutions was converted into supramolecular assembled gels, through the addition of transition metal ions (Ni2+, Co2+, Fe2+, and Zn2+). In particular, a supramolecular complex gel with Zn2+, which is a metal with a lower binding affinity, demonstrated fast self-healing properties, without any additional external stimuli, and its mechanical properties were completely recovered.

Evaluation of Ruthenium Catalysts for Ring-Opening Metathesis Polymerization-Based Self-Healing Applications

2008 ◽  
Vol 20 (10) ◽  
pp. 3288-3297 ◽  
Author(s):  
Gerald O. Wilson ◽  
Mary M. Caruso ◽  
Neil T. Reimer ◽  
Scott R. White ◽  
Nancy R. Sottos ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ruthenium Catalysts ◽  
Self Healing ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization

Synthesis and Purification of Tunable High Tg Electro-Optical Polymers by Ring Opening Metathesis Polymerization

2011 ◽  
Author(s):  
Robert H. Lambeth ◽  
Joseph M. Dougherty ◽  
Joshua A. Orlicki ◽  
Adam M. Rawlett ◽  
Robert C. Hoffman ◽  
...  
Keyword(s):  
Ring Opening ◽  
Optical Polymers ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization

Surface modification of carbon fibres using ring-opening metathesis polymerization

2021 ◽  
Vol 145 ◽  
pp. 106374
Author(s):  
David J. Hayne ◽  
Filip Stojcevski ◽  
Daniel B. Knorr ◽  
Ngon T. Tran ◽  
Luke C. Henderson
Keyword(s):  
Surface Modification ◽  
Ring Opening ◽  
Carbon Fibres ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization
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