Impact behavior and modeling of engineering polymers

2003 ◽  
Vol 43 (1) ◽  
pp. 112-124 ◽  
Author(s):  
Y. Duan ◽  
A. Saigal ◽  
R. Greif ◽  
M. A. Zimmerman
Author(s):  
Gudrun A. Hutchins

In order to optimize the toughening effect of elastomers in engineering polymers, it is necessary to characterize the size, morphology and dispersion of the specific elastomer within the polymer matrix. For unsaturated elastomers such as butadiene or isoprene, staining with osmium tetroxide is a well established procedure. The residual carbon-carbon double bond in these materials is the reactive site and forms a 1,2-dilato complex with the OsO4. Incorporation of osmium tetroxide into the elastomer not only produces sufficient contrast for TEM, but also crosslinks the elastomer sufficiently so that ultramicrotomy can be accomplished at room temperature with minimal distortion.Blends containing saturated elastomers such as butyl acrylate (BA) and ethylene propylene diene monomer (EPDM) cannot be stained directly with OsO4 because effective reaction sites such as C=C or -NH2 are not available in sufficient number. If additional reaction sites can be introduced selectively into the elastomer by a chemical reaction or the absorption of a solvent, a modified, two-step osmium staining procedure is possible.


2008 ◽  
Vol 4 (1) ◽  
pp. 1-26
Author(s):  
Gábor Kalácska

Research was performed on the friction, wear and efficiency of plastic gears made of modern engineering polymers and their composites both in a clean environment (adhesive sliding surfaces) and in an environment contaminated with solid particles and dust (abrasive), with no lubrication at all. The purpose is to give a general view about the results of abrasive wear tests including seven soil types as abrasive media. At the first stage of the research silicious sand was applied between the meshing gears and the wear of plastic and steel gears was evaluated and analyzed from the point of different material properties (elongation at break, hardness, yield stress, modulus of elasticity) and its combinations. The different correlations between the experienced wear and material features are also introduced. At the second stage of the project the abrasive sand was replaced with different physical soil types. The abrasive wear of gears is plotted in the function of soil types. The results highlight on the considerable role of physical soil types on abrasive wear resistance and the conclusions contain the detailed wear resistance. The results offer a new tribology database for the operation and maintenance of agricultural machines with the opportunity of a better material selection according to the dominant soil type. This can finally result longer lifetime and higher reliability of wearing plastic/steel parts.


2021 ◽  
pp. 109963622199387
Author(s):  
Mathilde Jean-St-Laurent ◽  
Marie-Laure Dano ◽  
Marie-Josée Potvin

The effect of extreme cold temperatures on the quasi-static indentation and the low velocity impact behavior of woven carbon/epoxy composite sandwich panels with Nomex honeycomb core was investigated. Impact tests were performed at room temperature, –70°C, and –150°C. Two sizes of hemispherical impactor were used combined to three different impactor masses. All the impact tests were performed at the same initial impact velocity. The effect of temperature on the impact behavior is investigated by studying the load history, load-displacement curves and transmitted energy as a function of time curves. Impact damage induced at various temperatures was studied using different non-destructive and destructive techniques. Globally, more damages are induced with impact temperature decreasing. The results also show that the effect of temperature on the impact behavior is function of the impactor size.


Author(s):  
Florian Lange ◽  
Kristian S. Nielsen ◽  
Viktoria Cologna ◽  
Cameron Brick ◽  
Paul C. Stern
Keyword(s):  

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