Role of nitrogen–oxygen plasma functionalization of carbon nanotubes in epoxy nanocomposites

2018 ◽  
Vol 40 (S2) ◽  
pp. E1162-E1171 ◽  
Author(s):  
Teresa Tromm Steffen ◽  
Luis César Fontana ◽  
Jacimar Nahorny ◽  
Daniela Becker
2013 ◽  
Vol 2013 ◽  
pp. 1-14 ◽  
Author(s):  
Mohammad Reza Saeb ◽  
Ehsan Bakhshandeh ◽  
Hossein Ali Khonakdar ◽  
Edith Mäder ◽  
Christina Scheffler ◽  
...  

The current paper provides an overview to emphasize the role of functionalization of multiwalled carbon nanotubes (MWCNTs) in manipulating cure kinetics of epoxy nanocomposites, which itself determines ultimate properties of the resulting compound. In this regard, the most commonly used functionalization schemes, that is, carboxylation and amidation, are thoroughly surveyed to highlight the role of functionalized nanotubes in controlling the rate of autocatalytic and vitrification kinetics. The current literature elucidates that the mechanism of curing in epoxy/MWCNTs nanocomposites remains almost unaffected by the functionalization of carbon nanotubes. On the other hand, early stage facilitation of autocatalytic reactions in the presence of MWCNTs bearing amine groups has been addressed by several researchers. When carboxylated nanotubes were used to modify MWCNTs, the rate of such reactions diminished as a consequence of heterogeneous dispersion within the epoxy matrix. At later stages of curing, however, the prolonged vitrification was seen to be dominant. Thus, the type of functional groups covalently located on the surface of MWCNTs directly affects the degree of polymer-nanotube interaction followed by enhancement of curing reaction. Our survey demonstrated that most widespread efforts ever made to represent multifarious surface-treated MWCNTs have not been directed towards preparation of epoxy nanocomposites, but they could result in property synergism.


2021 ◽  
Vol 06 ◽  
Author(s):  
Raja Murugesan ◽  
Sureshkumar Raman ◽  
Arun Radhakrishnan

Background: Recently, Nanomaterials based nano-composite materials play the role of various field. Especially, Carbon nanotube based materials are involved in the bio-medical applications.Since, their exclusive and exciting property, researchers worldwide have extensively involved in trans-modulating the carbon nanotubes into a viable medico-friendly system. Objective: These active researches paved the path towards targeted drug delivery, diagnostic techniques, and bio-analytical applications. Despite these exciting properties, which accomplish the probable for biomedical applications, they hold Biosafety issues. Methods: This broad-spectrum review has discussed different aspects of carbon nanotubes and carbon nanotube-based systems related to biomedical applications. Results: Adding to this, a short chronological description of these tiny yet powerful particles given, followed by a discussion regarding their types, properties, methods of synthesis, scale-up, purification techniques and characterization aspects of carbon nanotubes. Conclusion: In the later part, the functionalization of carbon nanotubes was reviewed in detail, which is important to make them biocompatible and stable in biological systems and render them a great property of loading various biomolecules diagnostic and therapeutic moieties. Lastly, an inclusive description of the potential biomedical applications has been given followed by insights into the future.


RSC Advances ◽  
2016 ◽  
Vol 6 (110) ◽  
pp. 108840-108850 ◽  
Author(s):  
Rachit Malik ◽  
Colin McConnell ◽  
Noe T. Alvarez ◽  
Mark Haase ◽  
Seyram Gbordzoe ◽  
...  

In situ plasma functionalization during manufacturing of CNT/polymer composites.


2005 ◽  
Vol 98 (7) ◽  
pp. 074308 ◽  
Author(s):  
A. Felten ◽  
C. Bittencourt ◽  
J. J. Pireaux ◽  
G. Van Lier ◽  
J. C. Charlier

2014 ◽  
Vol 132 (4) ◽  
pp. n/a-n/a ◽  
Author(s):  
Leonel Matías Chiacchiarelli ◽  
Mariano Martín Escobar ◽  
José María Kenny ◽  
Luigi Torre ◽  
Analía Vazquez

2016 ◽  
Vol 95 ◽  
pp. 1-8 ◽  
Author(s):  
Jaemin Cha ◽  
Sunghwan Jin ◽  
Jae Hun Shim ◽  
Chong Soo Park ◽  
Ho Jin Ryu ◽  
...  

2015 ◽  
Vol 26 (2) ◽  
pp. 315-336 ◽  
Author(s):  
Shahzad Hussain ◽  
Roger Amade ◽  
Eric Jover ◽  
Enric Bertran

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