Surface modification of magnesium hydroxide sulfate hydrate whiskers and its toughness and reinforcement for polyvinyl chloride

2017 ◽  
Vol 39 (10) ◽  
pp. 3676-3685 ◽  
Author(s):  
Juan Gong ◽  
Weihong Guo ◽  
Kai Wang ◽  
Jiaoyang Xiong
2010 ◽  
Vol 256 (10) ◽  
pp. 3234-3239 ◽  
Author(s):  
Chuan Hui Gao ◽  
Xian Guo Li ◽  
Li Juan Feng ◽  
Shao Yan Lu ◽  
Jin Yan Liu

1997 ◽  
Vol 53 (3) ◽  
pp. 358-363 ◽  
Author(s):  
M. E. Fleet ◽  
S. W. Knipe

Magnesium hydroxide sulfate [2MgSO4.Mg(OH)2; MHS] is tetragonal with a = 7.454 (1), c = 12.885 (2) Å, V = 716.0 Å3, space group P43212, Z = 4 and D x 2.774 g cm−3. The structure (single-crystal X-ray, R = 0.025, wR = 0.023) comprises spiral (43) single chains of corner-shared Mg(2) octahedra cross-linked by SO4 tetrahedra and face-shared Mg(1) octahedra. A linear ternary group of face-shared Mg octahedra [Mg(2)—Mg(1)—Mg(2)] alternates with an unoccupied octahedral position in rows along [\overline 110]. A crystal of MHS was grown hydrothermally (0.15 GPa, 673 K) from gold-bearing Mg—S—O—H fluid. The MHS structure, with Mg(1) octahedra sharing two octahedral faces with Mg(2) octahedra, revises the structure assumed for the complex solid solution magnesium hydroxide sulfate hydrate and the related ocean-floor mineral caminite [2MgSO4.xMg(OH)2.(2 − 2x)H2O; 0.5 < x < 1.0]. The substitution reaction appears to be Mg(1)2+ ⇋ 2H+. The H-substituted MHS structure is distinguished from that of kieserite (MgSO4.H2O), which has straight single chains of corner-shared Mg octahedra.


2001 ◽  
Vol 3 (2) ◽  
pp. 151-156 ◽  
Author(s):  
Yi Ding ◽  
Huazhang Zhao ◽  
Yugang Sun ◽  
Guangtao Zhang ◽  
Hao Wu ◽  
...  

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