Flame retardant, thermal, and mechanical properties of glass fiber/nanoclay reinforced phenol-urea-formaldehyde foam

2015 ◽  
Vol 37 (8) ◽  
pp. 2323-2332 ◽  
Author(s):  
Xiangming Hu ◽  
Weimin Cheng ◽  
Wen Nie ◽  
Deming Wang
Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 741
Author(s):  
Zorana Kovačević ◽  
Sandra Flinčec Grgac ◽  
Sandra Bischof

This paper summarizes the results obtained in the course of the development of a specific group of biocomposites with high functionality of flame retardancy, which are environmentally acceptable at the same time. Conventional biocomposites have to be altered through different modifications, to be able to respond to the stringent standards and environmental requests of the circular economy. The most commonly produced types of biocomposites are those composed of a biodegradable PLA matrix and plant bast fibres. Despite of numerous positive properties of natural fibres, flammability of plant fibres is one of the most pronounced drawbacks for their wider usage in biocomposites production. Most recent novelties regarding the flame retardancy of nanocomposites are presented, with the accent on the agents of nanosize (nanofillers), which have been chosen as they have low or non-toxic environmental impact, but still offer enhanced flame retardant (FR) properties. The importance of a nanofiller’s geometry and shape (e.g., nanodispersion of nanoclay) and increase in polymer viscosity, on flame retardancy has been stressed. Although metal oxydes are considered the most commonly used nanofillers there are numerous other possibilities presented within the paper. Combinations of clay based nanofillers with other nanosized or microsized FR agents can significantly improve the thermal stability and FR properties of nanocomposite materials. Further research is still needed on optimizing the parameters of FR compounds to meet numerous requirements, from the improvement of thermal and mechanical properties to the biodegradability of the composite products. Presented research initiatives provide genuine new opportunities for manufacturers, consumers and society as a whole to create a new class of bionanocomposite materials with added benefits of environmental improvement.


2011 ◽  
Vol 393-395 ◽  
pp. 1012-1017 ◽  
Author(s):  
Yu Feng Ma ◽  
Wei Zhang ◽  
Ling Li ◽  
Ming Ming Zhang ◽  
Zeng Hui Cheng ◽  
...  

New composite foams were prepared by co-foaming of Melamine-Urea-Formaldehyde (MUF) resin and wood fiber in the closed mould at 70°C. The effects of amount of wood fiber on mechanical properties, brittleness, flame-retardant, insulation and microscopic structures of wood fiber-MUF foam were investigated. Results indicated that the flame-retardant properties increased, and the brittleness and mechanical properties decreased with the increase of the amount of wood fiber in composite foams. The addition of wood fiber resulted in more uniform cell size distribution and irregular cell shape, but had little effect on insulation properties.


2021 ◽  
Author(s):  
Zhenya Zhang ◽  
Kunpeng Cai ◽  
Yaxin Guo ◽  
Xiaohua Liu ◽  
Suqin He ◽  
...  

Abstract Halogen-free flame retardants are ideal plastic additives that meet carbon neutral requirements. In this work, halogen free flame retardant with glass fiber reinforced PA66/PPO composites were prepared by using coated red phosphorus (FRM-150B) and phosphorus-silicon flame retardant (WR6002). The mechanical properties, heat resistance, friction and wear properties and flame retardancy were carried out to evaluate the performances of composites using as structural parts that require heat resistance, dimensional stability and accuracy. It was found that the friction coefficient and wear volume of the composites were improved with the contents of glass fiber increased, as a result, PA66/PPO composites was obtained with excellent comprehensive performance when the content of compatilizer is 7%, the glass fiber was 30%, the content of FRM is 8% and the phosphorous-silicon flame retardant is 16%. The flame retardant effect of FRM-150B and WR6002 in PA66/PPO was presented in the condensed phase, the results showed that the composite material with 16% WR6002 forms a carbon layer with excellent thermal stability. On the other hand, the mechanical properties of composites were hardly affected, has important prospects in automotive components and household appliances


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