Abnormal increase of glass transition temperature of poly(propylene carbonate) modified with rubber particles

2012 ◽  
Vol 33 (9) ◽  
pp. 1530-1533 ◽  
Author(s):  
Xiang Wang ◽  
Zhuoxin Li ◽  
Xingzhong Cao ◽  
Baoyi Wang ◽  
Guicun Qi ◽  
...  
2014 ◽  
Vol 904 ◽  
pp. 74-77 ◽  
Author(s):  
Qu Li ◽  
Heng Wu ◽  
Si Yuan Xie ◽  
Jiao Sun ◽  
Xing Hai Liu ◽  
...  

Biodegradable poly (propylene carbonate) (PPC) composite with a slight improvement in the thermal stability and tensile strength was successfully prepared by incorporating a low content of nano-SiO2. Tensile tests demonstrate the better mechanical properties of the composites prepared in this study. The obtained composites increases sharply from 1.57Mpa to 12.04Mpa by incorporating 5wt% nano-SiO2. Furthermore, the composites show approximately 8°C higher glass transition temperature (Tg) than that of neat PPC.The Tdmax of composite with 5wt% of nano-SiO2 was about 40°C higher than that of neat PPC.


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