The preparation and mechanism of permanently flame retardancy, antistatic, good toughness and high transparent poly(methyl methacrylate)

Author(s):  
Si Chen ◽  
Dandan Wu ◽  
Changbo Xu ◽  
Meng Ma ◽  
Yanqin Shi ◽  
...  
2012 ◽  
Vol 70 ◽  
pp. 58-66 ◽  
Author(s):  
H. Vahabi ◽  
M.A. Batistella ◽  
B. Otazaghine ◽  
C. Longuet ◽  
L. Ferry ◽  
...  

2015 ◽  
Vol 27 (2) ◽  
pp. 266-272 ◽  
Author(s):  
Saihua Jiang ◽  
Yulu Zhu ◽  
Yuan Hu ◽  
Guohua Chen ◽  
Xingxing Shi ◽  
...  

2014 ◽  
Vol 911 ◽  
pp. 423-427
Author(s):  
Sai Hua Jiang ◽  
Siu Ming Lo ◽  
Yuan Hu

A novel poly (methyl methacrylate) (PMMA) based copolymer was synthesized by bulk copolymerization of methyl methacrylate (MMA) and a phosphorus-containing monomer, acryloxyethyl phenoxy phosphorodiethyl amidate (AEPPA). The chemical structure of AEPPA was confirmed by FTIR,1H NMR and31P NMR. The structure of copolymers was characterized using FTIR. TGA results indicate that the thermal stability of copolymers was remarkably enhanced with the addition of APEEA. LOI and MCC results suggest that the flame retardancy of copolymers was also improved. Detailed flame-retardant mechanism is proposed. The char formation during degradation caused by APEEA plays a key role in the property improvements.


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