The influence of structural and charge transport properties of PEDOT : PSS layers on the photovoltaic properties of polymer solar cells

Author(s):  
A.K. Aimukhanov ◽  
X.S. Rozhkova ◽  
B.R. Ilyassov ◽  
A.K. Zeinidenov ◽  
N. Nuraje
2020 ◽  
Vol 8 (40) ◽  
pp. 21070-21083 ◽  
Author(s):  
Duyen K. Tran ◽  
Amélie Robitaille ◽  
I. Jo Hai ◽  
Xiaomei Ding ◽  
Daiki Kuzuhara ◽  
...  

This work provides a unified understanding on how polymer molecular weight influences the blend photophysics, blend morphology, charge transport, and photovoltaic properties of all-polymer solar cells.


RSC Advances ◽  
2016 ◽  
Vol 6 (66) ◽  
pp. 61809-61820 ◽  
Author(s):  
Yuanzuo Li ◽  
Chaofan Sun ◽  
Dawei Qi ◽  
Peng Song ◽  
Fengcai Ma

Three novel copolymers were designed based on BSeTT, QTT, BDT-DTBTBPz and BDT-DTBTBQx. Their properties of ground state and excited state were calculated via DFT/TDDFT methods. The charge moves from polymers to PC60BM.


2016 ◽  
Vol 7 (11) ◽  
pp. 6649-6661 ◽  
Author(s):  
Jae Hoon Yun ◽  
Sungmin Park ◽  
Jin Hyuck Heo ◽  
Hyo-Sang Lee ◽  
Seongwon Yoon ◽  
...  

Effects of fluorine substitution of small molecular semiconductor on charge transport and photovoltaic properties are systematically studied.


2021 ◽  
Author(s):  
Seok Woo Lee ◽  
MD Waseem Hussain ◽  
Sanchari Shome ◽  
Su Ryong Ha ◽  
Jae Taek Oh ◽  
...  

Abstract In this study, strong electron-withdrawing fluorine (F) and cyano (CN) substituents are selectively incorporated into the quinoxaline unit of two-dimensional (2D) D–A-type polymers to investigate their effects on the photovoltaic properties of the polymers. To construct the 2D polymeric structure, electron-donating benzodithiophene and methoxy-substituted triphenylamine are directly linked to the horizontal and vertical directions of the quinoxaline acceptor, respectively. After analyzing the structural, optical, and electrochemical properties of the resultant F- and CN-substituted polymers, labeled as PBCl-MTQF and PBCl-MTQCN, respectively, inverted-type polymer solar cells with a non-fullerene Y6 acceptor are fabricated to investigate the photovoltaic performances of the polymers. It is discovered that the maximum power conversion efficiency of PBCl-MTQF is 7.48%, whereas that of PBCl-MTQCN is limited to 3.10%. This significantly reduced PCE of the device based on PBCl-MTQCN is ascribed to the formation of irregular, large aggregates in the active layer, which can readily aggravate the charge recombination and charge transport kinetics of the device. Therefore, the photovoltaic performance of 2D quinoxaline-based D–A-type polymers is significantly affected by the type of electron-withdrawing substituent.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Seok Woo Lee ◽  
MD. Waseem Hussain ◽  
Sanchari Shome ◽  
Su Ryong Ha ◽  
Jae Taek Oh ◽  
...  

AbstractIn this study, strong electron-withdrawing fluorine (F) and cyano (CN) substituents are selectively incorporated into the quinoxaline unit of two-dimensional (2D) D–A-type polymers to investigate their effects on the photovoltaic properties of the polymers. To construct the 2D polymeric structure, electron-donating benzodithiophene and methoxy-substituted triphenylamine are directly linked to the horizontal and vertical directions of the quinoxaline acceptor, respectively. After analyzing the structural, optical, and electrochemical properties of the resultant F- and CN-substituted polymers, labeled as PBCl-MTQF and PBCl-MTQCN, respectively, inverted-type polymer solar cells with a non-fullerene Y6 acceptor are fabricated to investigate the photovoltaic performances of the polymers. It is discovered that the maximum power conversion efficiency of PBCl-MTQF is 7.48%, whereas that of PBCl-MTQCN is limited to 3.52%. This significantly reduced PCE of the device based on PBCl-MTQCN is ascribed to the formation of irregular, large aggregates in the active layer, which can readily aggravate the charge recombination and charge transport kinetics of the device. Therefore, the photovoltaic performance of 2D quinoxaline-based D–A-type polymers is significantly affected by the type of electron-withdrawing substituent.


RSC Advances ◽  
2015 ◽  
Vol 5 (41) ◽  
pp. 32891-32896 ◽  
Author(s):  
Xinyuan Zhang ◽  
Kezhi Zheng ◽  
Chunyu Liu ◽  
Hao Li ◽  
Zhiqi Li ◽  
...  

NaLuF4:Yb,Tm NRs were doped in a PCDTBT:PCBM solar cell to improve the current and fill factor, leading to a PCE of 7.175%.


2020 ◽  
Vol 8 (4) ◽  
pp. 1900877 ◽  
Author(s):  
Aleksandra Furasova ◽  
Pavel Voroshilov ◽  
Enrico Lamanna ◽  
Alexey Mozharov ◽  
Anton Tsypkin ◽  
...  

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