Highly flame retardant photocured paper coatings and printability behavior

2020 ◽  
Vol 31 (11) ◽  
pp. 2647-2658
Author(s):  
Arif Ozcan ◽  
Nemanja Kasikovic ◽  
Emine Arman Kandirmaz ◽  
Stefan Durdevic ◽  
Sasa Petrovic
Keyword(s):  
Flame Retardant ◽  
Paper Coatings

scholarly journals The production of flame retardant paper with DOPO

2020 ◽  
Author(s):  
Hatice Birtane ◽  
Keyword(s):  
Flame Retardant ◽  
Chemical Structure ◽  
Flame Retardants ◽  
Contact Angles ◽  
Flame Retardant Property ◽  
Paper Coatings ◽  
Coated Papers ◽  
Charring Agent ◽  
Coating Formulation ◽  
Intumescent Flame Retardants

Flame retardant property to paper increases the use of paper and the value of paper products. The flame retardant property was achieved by the addition of an organophosphorus agent to the paper. A great deal of research has been done on 9,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) derivatives as flame retardants. To apply the flame retardant property in condensed phase, DOPO derivative materials are generally used as an acid source for intumescent flame retardants to promote dehydration and carbonization of the charring agent to form a continuous layer of carbon. In this study, In order to prepare a flame retardant paper coating, DOPO derivative was synthesized with 3-aminophenyl sulfone, and benzaldehyde reaction and the chemical structure of DOPO is illuminated by ATR-FTIR then paper was coating with a flame retardant coating formulation ingredient with DOPO. The paper’s properties were investigated. Surface energy of coated papers and contact angles were determined with goniometer. Printability parameters such as color, gloss, surface tension were examined. The results the study DOPO added paper coatings improve the paper flame retardancy.

Evaluation of deep drawability of flame-retardant magnesium alloy sheets

2019 ◽  
Vol 9 (2) ◽  
pp. 182-191
Author(s):  
Akihiro Minami ◽  
Hirokazu Tamura ◽  
Hidetoshi Sakamoto ◽  
Yoshifumi Ohbuchi ◽  
Yasuo Marumo
Keyword(s):  
Magnesium Alloy ◽  
Flame Retardant ◽  
Deep Drawability

Mechanical and Flammability Properties of Green Polyurethane Foam with Alumina Trihydrate as Flame Retardant

2017 ◽  
Author(s):  
Amanda Silva ◽  
Enio Henrique Pires da Silva ◽  
Danilo Janes ◽  
Romeu Rony Cavalcante da Costa ◽  
Giovanna Gabriela Crem Silva
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foam ◽  
Alumina Trihydrate

Synthesis of Hexaphenoxycyclotriphosphazene with Allyl Group and Application in Flame Retardant Acrylate Resin

2012 ◽  
Vol 29 (9) ◽  
pp. 1090
Author(s):  
Donghai YUAN ◽  
Anbin TANG ◽  
Jie HUANG ◽  
Hanbing MA
Keyword(s):  
Flame Retardant ◽  
Acrylate Resin

Preparation and Characterization of Soybean Oil-based Flame Retardant Rigid Polyurethane Foams Containing Phosphaphenanthrene Groups

2020 ◽  
Vol 17 (10) ◽  
pp. 760-771
Author(s):  
Qirui Gong ◽  
Niangui Wang ◽  
Kaibo Zhang ◽  
Shizhao Huang ◽  
Yuhan Wang
Keyword(s):  
Soybean Oil ◽  
Flame Retardant ◽  
Chemical Structure ◽  
Cell Structure ◽  
Polyurethane Foams ◽  
Limiting Oxygen Index ◽  
Rigid Polyurethane Foams ◽  
Degradation Activation Energy ◽  
Ft Ir

A phosphaphenanthrene groups containing soybean oil based polyol (DSBP) was synthesized by epoxidized soybean oil (ESO) and 9,10-dihydro-oxa-10-phosphaphenanthrene-10-oxide (DOPO). Soybean oil based polyol (HSBP) was synthesized by ESO and H2O. The chemical structure of DSBP and HSBP were characterized with FT-IR and 1H NMR. The corresponding rigid polyurethane foams (RPUFs) were prepared by mixing DSBP with HSBP. The results revealed apparent density and compression strength of RPUFs decreased with increasing the DSBP content. The cell structure of RPUFs was examined by scanning electron microscope (SEM) which displayed the cells as spherical or polyhedral. The thermal degradation and flame retardancy of RPUFs were investigated by thermogravimetric analysis, limiting oxygen index (LOI), and UL 94 vertical burning test. The degradation activation energy (Ea) of first degradation stage reduced from 80.05 kJ/mol to 37.84 kJ/mol with 80 wt% DSBP. The RUPF with 80 wt% DSBP achieved UL94 V-0 rating and LOI 28.3. The results showed that the flame retardant effect was mainly in both gas phase and condensed phase.

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