Sulfonated poly (styrene-co-ethylene glycol dimethacrylate) with attractive ion exchange capacity

2018 ◽  
Vol 29 (11) ◽  
pp. 2759-2765 ◽  
Author(s):  
Thiago R. Theodoro ◽  
Joslaine R. Dias ◽  
Júlia L. Penariol ◽  
Juliana O.V. Moura ◽  
Leandro G. Aguiar
Keyword(s):  
Ion Exchange ◽  
Ethylene Glycol ◽  
Exchange Capacity ◽  
Ethylene Glycol Dimethacrylate ◽  
Glycol Dimethacrylate ◽  
Ion Exchange Capacity ◽  
Sulfonated Poly

Effects of chemical modification on the performance evaluation of photoinitiated, dispersion-polymerized poly(methyl methacrylate-co-ethylene glycol dimethacrylate-co-vinylbenzyl chloride) microsphere

2020 ◽  
pp. 096739112091786
Author(s):  
Norhayati Abdullah ◽  
Rabiatul A. Mahmod ◽  
Rohayu Jusoh ◽  
Mohammad Dalour Hossent Beg ◽  
Muhammad Remanul Islam
Keyword(s):  
Ethylene Glycol ◽  
Methyl Methacrylate ◽  
High Performance ◽  
Dispersion Polymerization ◽  
Solid Phase ◽  
Exchange Capacity ◽  
Ethylene Glycol Dimethacrylate ◽  
Glycol Dimethacrylate ◽  
Poly Methyl Methacrylate ◽  
Polymer Resin

Poly(methyl methacrylate- co-ethylene glycol dimethacrylate- co-vinylbenzyl chloride) microsphere was prepared by dispersion polymerization, initiated by light using water/ethanol mixture. The sulfonated hypercrosslinked (HXL) polymer resin was synthesized via three stages, namely, precursor synthesis (photoinitiated dispersion polymerization), post-polymerization after hypercrosslinking reaction, and post-polymerization before hypercrosslinking reaction. The optimized precursor was functionalized before the hypercrosslinking reaction to investigate its ion-exchange capacity, specific surface area (SSA), morphology, and thermal stability. Post-polymerization after hypercrosslinking reaction showed that the chlorine content and SSA are higher than post-polymerization before hypercrosslinking reaction. HXL reaction took place using Friedel–Crafts alkylation with the aid of FeCl3 catalyst. Lewis acid (FeCl3) also played a significant role which contributed to high SSA of the HXL polymer. The particles produced from photoinitiated dispersion polymerization have advantages and could be used in solid-phase extraction, drug delivery, and high-performance liquid chromatography.

scholarly journals Synthesis and investigation of sulfonated poly(p-phenylene)-based ionomers with precisely controlled ion exchange capacity for use as polymer electrolyte membranes

RSC Advances ◽  
2020 ◽  
Vol 10 (22) ◽  
pp. 12810-12822 ◽  
Author(s):  
Miru Yoshida-Hirahara ◽  
Satoshi Takahashi ◽  
Masahiro Yoshizawa-Fujita ◽  
Yuko Takeoka ◽  
Masahiro Rikukawa
Keyword(s):  
Ion Exchange ◽  
Polymer Electrolyte ◽  
Exchange Capacity ◽  
Polymer Electrolyte Membranes ◽  
Ion Exchange Capacity ◽  
Step Procedure ◽  
Electrolyte Membranes ◽  
Sulfonated Polymers ◽  
Sulfonated Poly

Poly(p-phenylene)-based sulfonated polymers with well-controlled IECs were synthesized via a three-step procedure including preceding sulfonation of precursor monomers.

Synthesis and Characterization of Multi-Sulfonated Poly(Aryl Ether Ketone)s Proton Exchange Membranes

2007 ◽  
Vol 544-545 ◽  
pp. 1065-1068 ◽  
Author(s):  
Dong Hoon Lee ◽  
Hye Suk Park ◽  
Dong Wan Seo ◽  
Tae Whan Hong ◽  
Whan Gi Kim
Keyword(s):  
Ion Exchange ◽  
Exchange Capacity ◽  
Proton Exchange ◽  
Condensation Polymerization ◽  
Aryl Ether ◽  
Scanning Calorimetry ◽  
Ion Exchange Capacity ◽  
Aryl Ether Ketone ◽  
Ether Ketone ◽  
Sulfonated Poly

A series of sulfonated poly(aryl ether ketone)s were prepared by condensation polymerization with bisphenol A and 1,2-bis(4-fluorobenzoyl)-3,6-diphenylbenzene, and followed by sufonation with chlorosulfonic acid. The polymers were characterized by Fourier transform infra-red (FTIR) and ion exchange capacity (IEC) to verify sulfonation. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) were carried out to investigate the thermal stability of the prepared membranes. The membranes were found to possess all the requisite properties; Ion exchange capacity (3.31meq./g), glass transition temperatures (207-230°C), and low affinity towards methanol (2.04x10-6-4.15x10-7 cm2/S).

Equilibrium Sorptions in Heterogeneous Ion Exchange Membranes

1992 ◽  
Vol 57 (9) ◽  
pp. 1905-1914
Author(s):  
Miroslav Bleha ◽  
Věra Šumberová
Keyword(s):  
Experimental Data ◽  
Ion Exchange ◽  
Total Content ◽  
Distribution Coefficients ◽  
Exchange Capacity ◽  
Ion Exchange Membranes ◽  
Ion Exchange Capacity ◽  
Equilibrium Sorption ◽  
Inhomogeneity Factor

The equilibrium sorption of uni-univalent electrolytes (NaCl, KCl) in heterogeneous cation exchange membranes with various contents of the ion exchange component and in ion exchange membranes Ralex was investigated. Using experimental data which express the concentration dependence of equilibrium sorption, validity of the Donnan relation for the systems under investigation was tested and values of the Glueckauf inhomogeneity factor for Ralex membranes were determined. Determination of the equilibrium sorption allows the effect of the total content of internal water and of the ion-exchange capacity on the distribution coefficients of the electrolyte to be determined.

Gold (Au) selective adsorption using polyeugenol based ionic imprinted polymer with ethylene glycol dimethacrylate crosslink

2020 ◽  
Author(s):  
M. Cholid Djunaidi ◽  
Nor Basid Adiwibawa Prasetya ◽  
Didik Setiyo Widodo ◽  
Retno Ariadi Lusiana ◽  
Pardoyo
Keyword(s):  
Ethylene Glycol ◽  
Selective Adsorption ◽  
Ethylene Glycol Dimethacrylate ◽  
Glycol Dimethacrylate ◽  
Imprinted Polymer
Sign in / Sign up

Export Citation Format

Share Document