Synthesis, characterization, processability, mechanical properties, flame retardant, and oil resistance of chlorinated acrylonitrile butadiene rubber

2018 ◽  
Vol 29 (8) ◽  
pp. 2165-2173 ◽  
Author(s):  
A. Nihmath ◽  
M. T. Ramesan
2020 ◽  
pp. 28-35
Author(s):  
Uthai Thepsuwan ◽  
Weenusarin Intiya ◽  
Promsak Sa-Nguanthammarong ◽  
Pongdhorn Sae-oui ◽  
Chakrit Sirisinha ◽  
...  

The influences of two phenolic resins, that is, cashew nut oil modified phenol-formaldehyde resin (CN-m-PF) and Bakelite moulding powder (BMP), on properties of carbon black filled acrylonitrile butadiene rubber (NBR) were investigated and compared. Processability, cure characteristics, mechanical properties, thermal ageing resistance, and oil resistance of the NBR filled with various contents of phenolic resins (0-60 phr) were determined. The addition of both resins leads to a prolonged cure time with a greater value of torque difference. Regardless of the resin type, the improvement of compound processability and the enhancement of modulus and hardness of the NBR vulcanisates are observed with increasing resin content. However, many mechanical properties such as tensile strength, elongation at break and abrasion resistance are deteriorated. Thermal ageing resistance of the NBR vulcanisate is slightly improved in the presence of both resins, probably due to the dilution of NBR with the high heat-resistant phenol-formaldehyde resins. Results also disclose that all NBR vulcanisates demonstrate excellent oil resistance, regardless of the resin type and content. At any given resin content, CN-m-PF gives a better processability, higher stiffness and greater mechanical properties than BMP. However, due to its lower cost, BMP can be used to enhance stiffness of NBR vulcanisates without the risk of processing problem.


Author(s):  
István Zoltán Halász ◽  
Tamás Bárány

In this work the effect of cyclic butylene terephthalate (CBT) was studied on the curing, rheological, morphological and mechanical properties of styrene butadiene rubber (SBR), oil extended styrene butadiene rubber (oSBR), acrylonitrile butadiene rubbers (NBR) with various acrylonitrile (AN) content and a carboxylated acrylonitrile butadiene rubber (XNBR). The effect of CBT on the oil resistance of the NBR and XNBR based compounds was also investigated. Viscosities of the uncured compounds were significantly decreased by CBT and it also acted as a semi-active filler, effectively reinforcing the tested rubbers, therefore it is suggested to be a bifunctional additive for tested rubbers. CBT also showed to have a positive effect on the oil resistance of NBR compounds.


2021 ◽  
pp. 096739112110313
Author(s):  
Ahmed Abdel-Hakim ◽  
Soma A el-Mogy ◽  
Ahmed I Abou-Kandil

Blending of rubber is an important route to modify properties of individual elastomeric components in order to obtain optimum chemical, physical, and mechanical properties. In this study, a novel modification of styrene butadiene rubber (SBR) is made by employing acrylic rubber (ACM) to obtain blends of outstanding mechanical, dynamic, and oil resistance properties. In order to achieve those properties, we used a unique vulcanizing system that improves the crosslink density between both polymers and enhances the dynamic mechanical properties as well as its resistance to both motor and break oils. Static mechanical measurements, tensile strength, elongation at break, and hardness are improved together with dynamic mechanical properties investigated using dynamic mechanical analyses. We also proposed a mechanism for the improvement of crosslink density and consequently oil resistance properties. This opens new opportunities for using SBR/ACM blends in oil sealing applications that requires rigorous mechanical and dynamic mechanical properties.


2015 ◽  
Vol 133 (4) ◽  
pp. n/a-n/a ◽  
Author(s):  
Peng Yu ◽  
Hui He ◽  
Can Jiang ◽  
Yunchao Jia ◽  
Dongqing Wang ◽  
...  

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