Flame-retardant rigid polyurethane foam with a phosphorus-nitrogen single intumescent flame retardant

2017 ◽  
Vol 29 (1) ◽  
pp. 668-676 ◽  
Author(s):  
Chao Wang ◽  
Yicheng Wu ◽  
Yingchun Li ◽  
Qian Shao ◽  
Xingru Yan ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foam ◽  
Intumescent Flame Retardant ◽  
Rigid Polyurethane Foam

Halogen Free flame retardant rigid polyurethane foam with a novel phosphorus−nitrogen intumescent flame retardant

2013 ◽  
Vol 131 (11) ◽  
pp. n/a-n/a ◽  
Author(s):  
Deng-Hui Wu ◽  
Pei-Hua Zhao ◽  
Ya-Qing Liu ◽  
Xue-Yi Liu ◽  
Xiao-feng Wang
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foam ◽  
Intumescent Flame Retardant ◽  
Rigid Polyurethane Foam ◽  
Halogen Free

The Study of Melamine Modified by Imidazolium Based Ionic Liquid [BMIM]PF6 on the Flame Retardancy of Rigid Polyurethane Foam

2014 ◽  
Vol 1030-1032 ◽  
pp. 241-245 ◽  
Author(s):  
Yan Wei Li
Keyword(s):  
Ionic Liquid ◽  
Flame Retardant ◽  
Polyurethane Foam ◽  
Fire Retardant ◽  
Rigid Polyurethane Foam ◽  
Flame Resistance ◽  
Initial Decomposition Temperature ◽  
Noticeable Effect ◽  
Rigid Foam ◽  
Flame Retardant Properties

In this paper, the effect of C3H6N6modified by imidazolium based Ionic Liquid 1-butyl-methylimidazolium hexafluorophosphate ([BMIM]PF6) on polyurethane rigid foam flame retardant properties was conducted.The results show that the flame retardant properties of C3H6N6 modified with Ionic Liquid significantly increased and the LOI increased form 22.3 to 24.5. In the modification process, the ionic liquid mass have a very noticeable effect to the flame retardant property and when [BMIM]PF6 and C3H6N6 in quality was 4:6, Fire-retardant effect was best.Compared with the prior to the modification, C3H6N6 modified can increase effective Flame resistance of materials, horizontal burning speed from 67.6mm/min down to 33.4mm/min.Thermal degradation data show that C3H6N6 modified could improve initial decomposition temperature and reminder yield of rigid polyurethane foam,and then heat release reduced, the decomposition controlled,thermal stability increased.

scholarly journals Synthesis of a DOPO-triazine additive and its flame-retardant effect in rigid polyurethane foam

e-Polymers ◽  
2019 ◽  
Vol 19 (1) ◽  
pp. 235-243 ◽  
Author(s):  
Lin Liu ◽  
Rui Lv
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foam ◽  
Cell Structure ◽  
Rigid Polyurethane Foam ◽  
Flame Resistance ◽  
Limiting Oxygen Index ◽  
Flame Retarded ◽  
Flame Retardant Properties ◽  
Mechanical Performances ◽  
Halogen Free

AbstractA DOPO (9,10-dihydro-9-oxa-10-phosphaphen-anthrene-10-oxide)-based halogen-free flame retardant (ODOPM-CYC) was synthesized and incorporated in rigid polyurethane foam (RPUF). The structure of ODOPM-CYC was characterized by Fourier transform infrared spectra (FTIR), 1H NMR and 31P NMR. The effects of ODOPM-CYC on the flame resistance, mechanical performances, thermal properties and cell structure of RPUF were also investigated. The results showed that the incorporation of ODOPM-CYC strikingly enhanced flame retardant properties of RPUF. The flame retarded RPUF acquired a limiting oxygen index (LOI) value of 26% and achieved UL-94 V-0 rating with the phosphorus content of 3 wt%. The smoke production rate (SPR) also showed an obvious decrease and total smoke release (TSR) was 39.8% lower than that of neat RPUF. Besides, the results demonstrated that the incorporation of ODOPM-CYC provided RPUF better thermal stability but did not show any obvious influence on its thermal conductivity.

Effect of aluminum diethylphosphinate on flame retardant and thermal properties of rigid polyurethane foam composites

2019 ◽  
Vol 140 (2) ◽  
pp. 625-636 ◽  
Author(s):  
Gang Tang ◽  
Lin Zhou ◽  
Ping Zhang ◽  
Zhongqiang Han ◽  
Depeng Chen ◽  
...  
Keyword(s):  
Thermal Properties ◽  
Flame Retardant ◽  
Polyurethane Foam ◽  
Rigid Polyurethane Foam

Dependence of flame-retardant properties on density of expandable graphite filled rigid polyurethane foam

2007 ◽  
Vol 104 (5) ◽  
pp. 3347-3355 ◽  
Author(s):  
Xiang-Cheng Bian ◽  
Jian-Hua Tang ◽  
Zhong-Ming Li ◽  
Zhong-Yuan Lu ◽  
Ai Lu
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foam ◽  
Expandable Graphite ◽  
Rigid Polyurethane Foam ◽  
Flame Retardant Properties
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