Synthesis of a novel phosphorus-containing curing agent and its effects on the flame retardancy, thermal degradation and moisture resistance of epoxy resins

2015 ◽  
Vol 27 (7) ◽  
pp. 860-871 ◽  
Author(s):  
Hongkun Zhang ◽  
Miaojun Xu ◽  
Bin Li
Keyword(s):  
Thermal Degradation ◽  
Flame Retardancy ◽  
Epoxy Resins ◽  
Moisture Resistance ◽  
Curing Agent ◽  
Phosphorus Containing

scholarly journals A bio-based phosphaphenanthrene-containing derivative modified epoxy thermosets with good flame retardancy, high mechanical properties and transparency

RSC Advances ◽  
2021 ◽  
Vol 11 (49) ◽  
pp. 30943-30954
Author(s):  
Wei Peng ◽  
Yu-xuan Xu ◽  
Shi-bin Nie ◽  
Wei Yang
Keyword(s):  
Mechanical Properties ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
Epoxy Resins ◽  
Flame Retardants ◽  
The Past ◽  
Phosphorus Containing ◽  
Modified Epoxy

Phosphorus-containing flame retardants have received huge interest for improving the flame retardant behavior of epoxy resins (EP) over the past few decades.

Kinetics Study of Thermal Degradation of Epoxy Resins Modified with 2-(Diphenylphosphinyl)-1, 4-Benzenediol

2014 ◽  
Vol 1053 ◽  
pp. 240-244
Author(s):  
Xiu Juan Tian ◽  
Zhong Wei Wang ◽  
Jun Gao
Keyword(s):  
Thermal Degradation ◽  
Epoxy Resins ◽  
Phosphorus Content ◽  
Degradation Kinetics ◽  
Thermal Degradation Kinetics ◽  
Ozawa Method ◽  
Air Atmosphere ◽  
Phosphorus Containing ◽  
Modified Epoxy ◽  
Kinetics Of

Phosphorus-containing epoxy resins with different phosphorus content were obtained from 2-(Diphenylphosphinyl)-1, 4-benzenediol (DPO-HQ) and biphenyl-A epoxy resin by crosslinking with 4, 4’-diaminodiphenylsulfone (DDS). The thermal degradation kinetics of the modified epoxy resins containing different phosphorus content were investigated by dynamic thermogravimetric analysis (TGA) under air atmosphere with different heating rate. The degradation of epoxy resins containing flame retardant components were found to be changed. The additive of phosphorus increases the carbon residue and improves the thermal stability at elevated temperature. The kinetics of thermal degradation was evaluated by Kissinger method and Flynn-Wall-Ozawa method, which do not require knowledge of the reaction mechanism. The results showed that the activation energies at lower degree of the degradation decreased with increasing of phosphorus content, while increased at higher degree of the degradation.

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