scholarly journals Enantioselective Synthesis of Acyclic Orthogonally Functionalized Compounds Bearing a Quaternary Stereocenter Using Chiral Ammonium Salt Catalysis

ChemistryOpen ◽  
2021 ◽  
Vol 10 (8) ◽  
pp. 756-759
Author(s):  
Katharina Röser ◽  
Bettina Berger ◽  
Michael Widhalm ◽  
Mario Waser
Keyword(s):  
Ammonium Salt ◽  
Enantioselective Synthesis ◽  
Quaternary Stereocenter

Palladium(ii)-catalyzed asymmetric C–H carbonylation to diverse isoquinoline derivatives bearing all-carbon quaternary stereocenters

2020 ◽  
Vol 56 (78) ◽  
pp. 11605-11608
Author(s):  
Yan Li ◽  
Xiu-Fen Cheng ◽  
Fan Fei ◽  
Tian-Rui Wu ◽  
Kang-Jie Bian ◽  
...  
Keyword(s):  
Late Stage ◽  
Enantioselective Synthesis ◽  
One Step ◽  
Quaternary Stereocenters ◽  
Quaternary Stereocenter ◽  
Isoquinoline Derivatives

Enantioselective synthesis of isoquinoline derivatives bearing an all-carbon quaternary stereocenter in one step via asymmetric Pd(ii)-catalyzed C–H activation and multiple late-stage derivatizations.

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