Fragmentation of 1,4,5,8-tetraazaphenanthrenes upon electron impact: A new example of structural integrity of gas phase heteroaromatic cations

1985 ◽  
Vol 20 (12) ◽  
pp. 733-737
Author(s):  
Raymonde Nasielski-Hinkens ◽  
Michel Kaisin ◽  
Robert Flammang ◽  
André Maquestiau
2001 ◽  
Vol 15 (22) ◽  
pp. 2127-2134 ◽  
Author(s):  
S. Prabhakar ◽  
Paramita Kar ◽  
S. P. Mirza ◽  
V. V. S. Lakshmi ◽  
K. Nagaiah ◽  
...  

1971 ◽  
Vol 43 (2) ◽  
pp. 162-171 ◽  
Author(s):  
Richard E. Grojean ◽  
John F. Rendina

2002 ◽  
Vol 8 (3) ◽  
pp. 233-246 ◽  
Author(s):  
Vladislav V. Zelenov ◽  
Elena V. Aparina ◽  
Alexander V. Loboda ◽  
Alexander S. Kukui ◽  
Alexander F. Dodonov ◽  
...  

Using a reactor with a flowing diffusion cloud coupled to a high-resolution, low-energy electron-impact ionization mass spectrometer, mechanistic, kinetic and thermochemical characteristics of gas-phase reactions with the participation of charged and neutral xenon oxides, xenon fluorides and xenon oxyfluorides have been investigated. Ionization energies for XeF, XeF2, XeF4, XeO3, XeO4, XeOF4 molecules and appearance energies for the ions formed from these molecules were obtained. Based on experimental and reference data, the enthalpies of XeO3 and XeOF4 formation were refined and a number of binding energies in the parent and fragment ions were calculated. For electron-impact ionization, the ionization cross-sections for Xe, XeF2, XeF4 and XeOF4 proved to correlate with a semi-empirical principle of full ionization. Based on the temperature dependencies of saturated vapor pressures for XeO4, XeOF4 and XeO2F2, their enthalpies of evaporation, sublimation and melting were determined. The mechanisms of gas-phase reactions between H atoms and neutral XeF2, XeF4, XeF6, XeO4 and XeOF4 were studied.


2007 ◽  
Vol 102 (4) ◽  
pp. 500-502 ◽  
Author(s):  
I. I. Shafranyosh ◽  
M. I. Sukhoviya

2015 ◽  
Vol 69 (1) ◽  
Author(s):  
Mykola Erdevdy ◽  
Pavlo Markush ◽  
Otto Shpenik ◽  
Vitalij Zvenihorodsky
Keyword(s):  

2014 ◽  
Vol 40 (1) ◽  
pp. 13-17 ◽  
Author(s):  
A. N. Zavilopulo ◽  
O. B. Shpenik ◽  
P. P. Markush ◽  
M. I. Mykyta

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