Influence of the temperature-dependent dielectric constant on the H/D isotope effects on the NMR chemical shifts and the hydrogen bond geometry of the collidine-HF complex in CDF3/CDClF2 solution

2001 ◽  
Vol 39 (S1) ◽  
pp. S91-S99 ◽  
Author(s):  
Ilja G. Shenderovich ◽  
Andrej P. Burtsev ◽  
Gleb S. Denisov ◽  
Nikolai S. Golubev ◽  
Hans-Heinrich Limbach
Keyword(s):  
Hydrogen Bond ◽  
Dielectric Constant ◽  
Chemical Shifts ◽  
Isotope Effects ◽  
Temperature Dependent ◽  
Nmr Chemical Shifts

Supplement To: OHO Hydrogen Bond Geometries and NMR Chemical Shifts: From Equilibrium Structures to Geometric H/D Isotope Effects, with Applications for Water, Protonated Water, and Compressed Ice

2009 ◽  
Vol 49 (2) ◽  
pp. s1-s36
Author(s):  
Hans-Heinrich Limbach ◽  
Peter M. Tolstoy ◽  
Natalia Pérez-Hernández ◽  
Jing Guo ◽  
Ilya G. Shenderovich ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Chemical Shifts ◽  
Isotope Effects ◽  
Nmr Chemical Shifts ◽  
Equilibrium Structures

OHO Hydrogen Bond Geometries and NMR Chemical Shifts: From Equilibrium Structures to Geometric H/D Isotope Effects, with Applications for Water, Protonated Water, and Compressed Ice

2009 ◽  
Vol 49 (2) ◽  
pp. 199-216 ◽  
Author(s):  
Hans-Heinrich Limbach ◽  
Peter M. Tolstoy ◽  
Natalia Pérez-Hernández ◽  
Jing Guo ◽  
Ilya G. Shenderovich ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Chemical Shifts ◽  
Isotope Effects ◽  
Nmr Chemical Shifts ◽  
Equilibrium Structures

Hydrogen Bond Geometries and Proton Tautomerism of Homoconjugated Anions of Carboxylic Acids Studied via H/D Isotope Effects on 13C NMR Chemical Shifts

2012 ◽  
Vol 116 (46) ◽  
pp. 11180-11188 ◽  
Author(s):  
Jing Guo ◽  
Peter M. Tolstoy ◽  
Benjamin Koeppe ◽  
Nikolai S. Golubev ◽  
Gleb S. Denisov ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Carboxylic Acids ◽  
13C Nmr ◽  
Chemical Shifts ◽  
Isotope Effects ◽  
Nmr Chemical Shifts ◽  
13C Nmr Chemical Shifts

Hydrogen/Deuterium-Isotope Effects on NMR Chemical Shifts and Symmetry of Homoconjugated Hydrogen-Bonded Ions in Polar Solution

2000 ◽  
Vol 122 (51) ◽  
pp. 12878-12879 ◽  
Author(s):  
Parwin Schah-Mohammedi ◽  
Ilja G. Shenderovich ◽  
Carsten Detering ◽  
Hans-Heinrich Limbach ◽  
Peter M. Tolstoy ◽  
...  
Keyword(s):  
Chemical Shifts ◽  
Isotope Effects ◽  
Polar Solution ◽  
Nmr Chemical Shifts ◽  
Hydrogen Deuterium ◽  
Deuterium Isotope Effects ◽  
Hydrogen Bonded

Deuterium Isotope Effects on13C NMR Chemical Shifts Reflect the Smaller Steric Size of CD3Compared to CH3Groups§

2000 ◽  
Vol 2 (25) ◽  
pp. 4111-4113 ◽  
Author(s):  
Kerstin Ibrom ◽  
Gunther Kohn ( ◽  
Kai-Uwe Boeckmann ◽  
Roswitha Kraft ◽  
Petra Holba-Schulz ◽  
...  
Keyword(s):  
Chemical Shifts ◽  
Isotope Effects ◽  
Nmr Chemical Shifts ◽  
Deuterium Isotope Effects

Tritium isotope effects on carbon-13 NMR chemical shifts

1986 ◽  
Vol 108 (6) ◽  
pp. 1356-1357 ◽  
Author(s):  
Cheryl H. Arrowsmith ◽  
Lars. Baltzer ◽  
A. Jerry. Kresge ◽  
Michael F. Powell ◽  
Yui S. Tang
Keyword(s):  
Chemical Shifts ◽  
Isotope Effects ◽  
Nmr Chemical Shifts

Cyclic trimers of phosphinic acids in polar aprotic solvent: symmetry, chirality and H/D isotope effects on NMR chemical shifts

2018 ◽  
Vol 20 (7) ◽  
pp. 4901-4910 ◽  
Author(s):  
V. V. Mulloyarova ◽  
I. S. Giba ◽  
M. A. Kostin ◽  
G. S. Denisov ◽  
I. G. Shenderovich ◽  
...  
Keyword(s):  
Aprotic Solvent ◽  
Chemical Shifts ◽  
Isotope Effects ◽  
Nmr Chemical Shifts ◽  
Polar Aprotic Solvent ◽  
Phosphinic Acids ◽  
Proton Chemical Shifts ◽  
Bonded Complexes ◽  
Hydrogen Bonded

By using NMR in liquefied gases, the stoichiometry of hydrogen-bonded complexes is determined via H/D isotope effects on proton chemical shifts.

scholarly journals 45Scandium NMR Investigations in Aqueous Solutions

1983 ◽  
Vol 38 (3) ◽  
pp. 317-321 ◽  
Author(s):  
E. Haid ◽  
D. Köhnlein ◽  
G. Kössler ◽  
O. Lutz ◽  
W. Messner ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Chemical Shifts ◽  
Isotope Effects ◽  
Larmor Frequency ◽  
Relaxation Rates ◽  
Nmr Chemical Shifts ◽  
Typical Behaviour ◽  
Solvent Isotope ◽  
Scandium Chloride ◽  
Solvent Isotope Effects

Abstract45Sc NMR chemical shifts, linewidths, and longitudinal relaxation rates have been measured in aqueous solutions of scandium chloride and sulphate as a function of the appropriate acid. A common typical behaviour of these parameters without sudden changes has been observed. Also signals in the basic range have been obtained. H2O -D2O solvent isotope effects on Larmor frequency and relaxation rates are presented.

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