Relativistic heavy atom effect on 13 C NMR chemical shifts initiated by adjacent multiple chalcogens

2018 ◽  
Vol 56 (8) ◽  
pp. 716-726 ◽  
Author(s):  
Yu.Yu. Rusakov ◽  
I.L. Rusakova
Daxue Huaxue ◽  
2016 ◽  
Vol 31 (3) ◽  
pp. 32-36
Author(s):  
Xu-Dong LIU ◽  
◽  
Hui-Li FAN ◽  
Jun-Ping XIAO

1987 ◽  
Vol 42 (3) ◽  
pp. 287-292 ◽  
Author(s):  
J. Fritze ◽  
W. Preetz ◽  
H. C. Marsmann

The point symmetries of the halogenohydrohexaborates within the nearly complete series XnB6H6-n2-, X = Cl, Br, I; n = 1-5, are determined from the 11B and 11B{1H} NMR spectra, which show characteristic features for homologous isostructural compounds related to the electronegativity of the substituents. The chemical shifts are mainly influenced by -I, +M, and in the case of X = I by the heavy atom effect. Along with a strong antipodal effect a slight vicinal influence between neighbours in the B6 cage is observed, increasing with the number of substituted atoms


2021 ◽  
Author(s):  
Ya-Fang Xiao ◽  
Jia-Xiong Chen ◽  
Wen-Cheng Chen ◽  
Xiuli Zheng ◽  
Chen Cao ◽  
...  

Applying the heavy-atom effect to TADF photosensitizers achieves ultra-high 1O2 generation (ФΔ = 0.91) by the synergetic effect of small ΔEST and considerable SOC.


2021 ◽  
pp. 2104646
Author(s):  
Hyung Suk Kim ◽  
Ja Yeon Lee ◽  
Seongjun Shin ◽  
Wonkyo Jeong ◽  
Sang Hoon Lee ◽  
...  

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