Effects of Reversible Chemical Reaction on Morphology and Domain Growth of Phase Separating Binary Mixtures with Viscosity Difference

2004 ◽  
Vol 13 (3) ◽  
pp. 280-289 ◽  
Author(s):  
Yanli Huo ◽  
Hongdong Zhang ◽  
Yuliang Yang
2003 ◽  
Vol 118 (21) ◽  
pp. 9830-9837 ◽  
Author(s):  
Yanli Huo ◽  
Xiuli Jiang ◽  
Hongdong Zhang ◽  
Yuliang Yang

1989 ◽  
Vol 44 (10) ◽  
pp. 2295-2310 ◽  
Author(s):  
G.F. Versteeg ◽  
J.A.M. Kuipers ◽  
F.P.H. Van Beckum ◽  
W.P.M. Van Swaaij

2013 ◽  
Vol 27 (21) ◽  
pp. 1350153
Author(s):  
WEN-QIANG FENG ◽  
KAI-MING WANG ◽  
YUE-JIN ZHU

In this paper, we present Monte Carlo simulations of A-B-diblock-copolymer ternary mixtures simultaneously undergoing phase separation and reversible chemical reaction A + B ⇌ C . The results demonstrate that the competition of chemical reaction and thermal diffusion dynamics co-determine the self-assembling morphology and growth kinetics of the reactive ternary mixtures. The role of the chemical reaction on the growth kinetics count mainly on the copolymer–polymer interaction strength Jp. If Jp < 1.0, the introduction of chemical reaction speeds up the domain growth; while for Jp > 1.0, the chemical reaction slows down the domain growth. The domain growth exponent decreases linearly with increasing of the copolymer–polymer interaction strength. At a later stage, 〈1, 0〉 and 〈0, 1〉 oriented strip pattern formations are observed when Jp is strong.


Author(s):  
Akira WADA ◽  
Kinji ASAKA ◽  
Tetsuya HORIUCHI ◽  
Koichi SUZUMORI ◽  
Gen ENDO ◽  
...  

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