Influence of the Processing Conditions on the Morphology and the Mechanical Properties of Polyamide 6-Carbon Fibre-Carbon Nano Tube-Compounds

2014 ◽  
Vol 338 (1) ◽  
pp. 8-16 ◽  
Author(s):  
Walter Michaeli ◽  
Christian Hopmann ◽  
Florian Puch
Polymers ◽  
2018 ◽  
Vol 10 (7) ◽  
pp. 779 ◽  
Author(s):  
Emanuele Parodi ◽  
Gerrit Peters ◽  
Leon Govaert

The effect of processing conditions during injection on the structure formation and mechanical properties of injection molded polyamide 6 samples was investigated in detail. A large effect of the mold temperature on the crystallographic properties was observed. Also the the effect of pressure and shear flow was taken in to consideration and analysed. The yield and failure kinetics, including time-to-failure, were studied by performing tensile and creep tests at several test temperatures and relative humidities. As far as mechanical properties are concerned, a strong influence of temperature and relative humidity on the yield stress and time-to-failure was found. A semi-empirical model, able to describe yield and failure kinetics, was applied to the experimental results and related to the crystalline phase present in the sample. In agreement with findings in the literature it is observed that for high mold temperatures the sample morphology is more stable with respect to humidity and temperature than in case of low mold temperatures and this effects could be successfully captured by the model. The samples molded at low temperatures showed, during mechanical testing, a strong evolution of the crystallographic properties when exposed to high testing temperature and high relative humidity, i.e., an increase of crystallinity or a crystal phase transition. This makes a full description of the mechanical behavior rather complicated.


2018 ◽  
Vol 1 (2) ◽  
Author(s):  
Camilo Zopp ◽  
Daisy Nestler ◽  
Nadine Buschner ◽  
Carola Mende ◽  
Sven Mauersberger ◽  
...  

For several years, thermoplastic hybrid laminates form a new class in the field of material compounds. These laminates consist of fibre-reinforced plastic prepregs and metal layers in alternating order. Compared to conventional thermosetting multilayer composites, these laminates are suitable for large-scale production and can be manufactured with significantly reduced cycle times in the thermoforming process.  In the framework of this contribution, the influence of the cooling rate of carbon fibre-reinforced thermoplastic composites and hybrid laminates was investigated with regard to crystallinity and the resulting mechanical properties. Polyamide 6 and thermoplastic polyurethane as matrix systems were examined, in particular.Additionally, the differential scanning calorimetry was used in order to investigate the influence of the cooling rate on the crystallisation behaviour. It could be determined that the cooling rate has a limited influence on the crystallisation of polyamide 6 and this influences the mechanical properties. Furthermore, a reliance of process parameters on the characteristics profile of composite materials and material compounds with thermoplastic polyurethane could be identified. Depending on process conditions, tensile, bending, and interlaminar shear properties fluctuate up to 20 % in fibre-reinforced laminates and up to 32 % in hybrid laminates. Moderate to fast cooling rates result in optimum mechanical characteristics of tensile properties in fibre-plastic-compounds. Fast to very fast cooling rates are advisable for bending and interlaminar shear properties. Highest tensile and bending characteristics are achieved in hybrid laminates by using fast to very fast cooling rates, while interlaminar shear properties tend to be highest in slow to moderate cooling rates.


Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1190 ◽  
Author(s):  
Cristina Monteserín ◽  
Miren Blanco ◽  
Nieves Murillo ◽  
Ana Pérez-Márquez ◽  
Jon Maudes ◽  
...  

Delamination and brittle matrix fracture have long since been the biggest problems in fibre-reinforced composites. Recently, the incorporation of electrospun nanofibre veils has been shown to be an effective method for improving the mechanical properties of these composites, without causing process problems and negatively affecting other mechanical properties. Thus, these nanofibres have the potential to be used as thickness-reinforcing materials in composites. This paper investigates the effect of incorporating standalone electrospun nanofibre veils made of two different types of polyamide 6 (PA6) on the mechanical properties of carbon fibre/epoxy composites. The influence of positioning the electrospun veils at different interlaminar positions of the laminate has also been investigated.


2010 ◽  
Vol 70 (14) ◽  
pp. 2063-2067 ◽  
Author(s):  
Shirley Zhiqi Shen ◽  
Stuart Bateman ◽  
Patrick McMahon ◽  
Mel Dell’Olio ◽  
Januar Gotama ◽  
...  

2015 ◽  
Vol 659 ◽  
pp. 659-665
Author(s):  
Supakit Chuaping ◽  
Thomas Mann ◽  
Rapeephun Dangtungee ◽  
Suchart Siengchin

The topic of this research work was to demonstrate the feasibility of a 3D-MID concept using injection molding technique and investigate the effects of two weld line types on the structure and mechanical properties such as tensile, flexural strength and morphology. In order to obtain more understanding of the bonds between polymer and metals, two different polymer bases of polyphthalamide (PPA) with the same type and amount of filler content were produced by injection molding at the different processing conditions. A mold was designed in such a way that weld and meld line can be produced with different angles by changing as insert inside of the mold. The mechanical properties such as stiffness, tensile strength and flexural strength were determined in tensile and flexural tests, respectively. The results showed in line with the expectation of high reduction on mechanical properties in area where weld/meld lines occurred. The result of tensile test was clearly seen that weld and meld line showed a considerable influence on mechanical properties. The reduction in tensile strength was approximately 58% according to weld line types, whereas in flexural strength was approximately 62%. On the other hand, the effect of the injection times and mold temperatures on the tensile strength were marginal.


2016 ◽  
Vol 51 (6) ◽  
pp. 783-795 ◽  
Author(s):  
Júlio C Santos ◽  
Luciano MG Vieira ◽  
Túlio H Panzera ◽  
André L Christoforo ◽  
Marco A Schiavon ◽  
...  

The work describes the manufacturing and testing of novel hybrid epoxy/carbon fibre composites with silica micro and poly-diallyldimethylammonium chloride-functionalised nanoparticles. A specific chemical dispersion procedure was applied using the poly-diallyldimethylammonium chloride to avoid clustering of the silica nanoparticles. The influence of the various manufacturing parameters, particles loading, and mechanical properties of the different phases has been investigated with a rigorous Design of Experiment technique based on a full factorial design (2131). Poly-diallyldimethylammonium chloride-functionalised silica nanoparticles were able to provide a homogenous dispersion, with a decrease of the apparent density and enhancement of the mechanical properties in the hybrid carbon fibre composites. Compared to undispersed carbon fibre composite laminates, the use of 2 wt% functionalised nanoparticles permitted to increase the flexural modulus by 47% and the flexural strength by 15%. The hybrid carbon fibre composites showed also an increase of the tensile modulus (9%) and tensile strength (5.6%).


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