A Facile and Highly Efficient Route to Amphiphilic Star‐Like Rod‐Coil Block Copolymer via a Combination of Atom Transfer Radical Polymerization with Thiol–Ene Click Chemistry

2020 ◽  
Vol 41 (5) ◽  
pp. 1900540 ◽  
Author(s):  
Xinglong Wang ◽  
Chunyan Zhao ◽  
Yuanyuan Li ◽  
Zhiqun Lin ◽  
Hui Xu
Keyword(s):  
Block Copolymer ◽  
Atom Transfer Radical Polymerization ◽  
Click Chemistry ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Highly Efficient ◽  
Efficient Route

ATRP Synthesis of PS-b-PtBMA and Preparation of Porous Film

2013 ◽  
Vol 364 ◽  
pp. 679-683
Author(s):  
Chang Hao Yan ◽  
Zhi Jiao Zhang ◽  
Hai Yan Chen ◽  
Zhong Yi Xie ◽  
Ting Zhu ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Catalyst System ◽  
Porous Film ◽  
Atom Transfer ◽  
H Nmr ◽  
Breath Figure ◽  
Breath Figure Method ◽  
End Group

The polystyrene with end group of Br was synthesized by using MBrP as the initiator, CuBr/ PMDETA as the catalyst system according to atom transfer radical polymerization (ATRP). The effect of reaction temperature was studied and the system was confirmed as the active polymerization. Then PS-Br and CuBr/ PMDETA were respectively used as macroinitiator and catalyst to polymerize tBMA according to atom transfer radical polymerization (ATRP). The structure of the product was characterized by GPCFTIR1H-NMR. The amphiphilic block copolymer was obtained after hydrolysis. And the honeycomb porous film was prepared by PS-b-PMAA through using breath figure method.

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