Controlled Synthesis of Block Copolymers by Mechanistic Transformation from Atom Transfer Radical Polymerization to Iniferter Process

Cansu Aydogan; Mustafa Ciftci; Yusuf Yagci

doi:10.1002/marc.201900109

Controlled Synthesis of Block Copolymers by Mechanistic Transformation from Atom Transfer Radical Polymerization to Iniferter Process

Macromolecular Rapid Communications ◽

10.1002/marc.201900109 ◽

2019 ◽

Vol 40 (14) ◽

pp. 1900109

Author(s):

Cansu Aydogan ◽

Mustafa Ciftci ◽

Yusuf Yagci

Keyword(s):

Block Copolymers ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Controlled Synthesis ◽

Atom Transfer

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Synthesis and characterization of amphiphilic and hydrophobic ABA-type tri-block copolymers using telechelic polyurethane as atom transfer radical polymerization macroinitiator

Colloid & Polymer Science ◽

10.1007/s00396-009-2149-2 ◽

2009 ◽

Vol 288 (2) ◽

pp. 181-188 ◽

Cited By ~ 10

Author(s):

Susanginee Nayak ◽

Hemant Verma ◽

Tharanikkarasu Kannan

Keyword(s):

Block Copolymers ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Synthesis And Characterization ◽

Atom Transfer

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Synthesis of Poly(methyl methacrylate)-b-poly(N-isopropylacrylamide) Block Copolymer by Redox Polymerization and Atom Transfer Radical Polymerization

Indonesian Journal of Chemistry ◽

10.22146/ijc.28645 ◽

2018 ◽

Vol 18 (3) ◽

pp. 537 ◽

Cited By ~ 3

Author(s):

Melahat Göktaş ◽

Guodong Deng

Keyword(s):

Block Copolymers ◽

Methyl Methacrylate ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Gel Permeation Chromatography ◽

High Yield ◽

Resonance Spectroscopy ◽

Atom Transfer ◽

Poly Methyl Methacrylate ◽

Redox Polymerization

Poly(methyl methacrylate)-b-poly(N-isopropylacrylamide) [PMMA-b-PNIPAM] block copolymers were obtained by a combination of redox polymerization and atom transfer radical polymerization (ATRP) methods in two steps. For this purpose, PMMA macroinitator (ATRP-macroinitiator) was synthesized by redox polymerization of methyl methacrylate and 3-bromo-1-propanol using Ce(NH4)2(NO3)6 as a catalyst. The synthesis of PMMA-b-PNIPAM block copolymers was carried out by means of ATRP of ATRP-macroinitiator and NIPAM at 60 °C. The block copolymers were obtained in high yield and high molecular weight. The characterization of products was accomplished by using multi instruments and methods such as nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, gel permeation chromatography, and thermogravimetric analysis.

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Synthesis of Block Copolymers Containing Polybutadiene Segments by Combination of Coordinative Chain Transfer Polymerization, Ring-Opening Polymerization, and Atom Transfer Radical Polymerization

Macromolecular Chemistry and Physics ◽

10.1002/macp.201400465 ◽

2014 ◽

Vol 216 (3) ◽

pp. 321-328 ◽

Cited By ~ 15

Author(s):

Feng Wang ◽

Bo Dong ◽

Heng Liu ◽

Jun Guo ◽

Wenjie Zheng ◽

...

Keyword(s):

Block Copolymers ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Ring Opening ◽

Chain Transfer ◽

Ring Opening Polymerization ◽

Atom Transfer ◽

Chain Transfer Polymerization

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Controlled synthesis of poly[(butyl methacrylate)-co -(butyl acrylate)] via activator regenerated by electron transfer atom transfer radical polymerization: insights and improvement

Polymer International ◽

10.1002/pi.4678 ◽

2014 ◽

Vol 63 (5) ◽

pp. 848-857 ◽

Cited By ~ 23

Author(s):

Kevin A Payne ◽

Paul HM Van Steenberge ◽

Dagmar R D'hooge ◽

Marie-Françoise Reyniers ◽

Guy B Marin ◽

...

Keyword(s):

Electron Transfer ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Butyl Acrylate ◽

Butyl Methacrylate ◽

Controlled Synthesis ◽

Atom Transfer

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Controlled Synthesis of Concentrated Polymer Brushes with Ultralarge Thickness by Surface-Initiated Atom Transfer Radical Polymerization under High Pressure

Macromolecules ◽

10.1021/acs.macromol.9b02072 ◽

2019 ◽

Vol 53 (1) ◽

pp. 132-137 ◽

Cited By ~ 5

Author(s):

Shu-Yao Hsu ◽

Yuzo Kayama ◽

Kohji Ohno ◽

Keita Sakakibara ◽

Takeshi Fukuda ◽

...

Keyword(s):

High Pressure ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Polymer Brushes ◽

Controlled Synthesis ◽

Atom Transfer

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Catalytic Halogen Exchange in Supplementary Activator and Reducing Agent Atom Transfer Radical Polymerization for the Synthesis of Block Copolymers

Macromolecular Rapid Communications ◽

10.1002/marc.202000532 ◽

2020 ◽

pp. 2000532

Author(s):

Francesco De Bon ◽

Carlos M. R. Abreu ◽

Arménio C. Serra ◽

Armando Gennaro ◽

Jorge F. J. Coelho ◽

...

Keyword(s):

Block Copolymers ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Reducing Agent ◽

Atom Transfer ◽

Halogen Exchange

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Poly(methyl methacrylate)−Poly(caprolactone) AB and ABA Block Copolymers by Combined Ring-Opening Polymerization and Atom Transfer Radical Polymerization

Macromolecules ◽

10.1021/ma070417q ◽

2007 ◽

Vol 40 (25) ◽

pp. 8887-8896 ◽

Cited By ~ 27

Author(s):

Michèle Schappacher ◽

Nicolas Fur ◽

Sophie M. Guillaume

Keyword(s):

Block Copolymers ◽

Methyl Methacrylate ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Ring Opening ◽

Ring Opening Polymerization ◽

Atom Transfer ◽

Poly Methyl Methacrylate ◽

Poly Caprolactone

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Synthesis of Block Copolymers by Combination of Atom Transfer Radical Polymerization and Visible Light-Induced Free Radical Promoted Cationic Polymerization

Macromolecular Rapid Communications ◽

10.1002/marc.201100641 ◽

2012 ◽

Vol 33 (4) ◽

pp. 309-313 ◽

Cited By ~ 43

Author(s):

Muhammet U. Kahveci ◽

Gokhan Acik ◽

Yusuf Yagci

Keyword(s):

Free Radical ◽

Block Copolymers ◽

Visible Light ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Cationic Polymerization ◽

Atom Transfer

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Direct synthesis of amphiphilic block copolymers, consisting of poly(methyl methacrylate) and poly(sodium styrene sulfonate) blocks through atom transfer radical polymerization

European Polymer Journal ◽

10.1016/j.eurpolymj.2008.03.005 ◽

2008 ◽

Vol 44 (6) ◽

pp. 1857-1864 ◽

Cited By ~ 18

Author(s):

Eudokia K. Oikonomou ◽

Elefterios K. Pefkianakis ◽

Georgios Bokias ◽

Joannis K. Kallitsis

Keyword(s):

Block Copolymers ◽

Methyl Methacrylate ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Direct Synthesis ◽

Amphiphilic Block Copolymers ◽

Atom Transfer ◽

Poly Methyl Methacrylate ◽

Styrene Sulfonate ◽

Sodium Styrene Sulfonate

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Synthesis of Amphiphilic Block Copolymers by Atom Transfer Radical Polymerization (ATRP)

Macromolecules ◽

10.1021/ma9804747 ◽

1998 ◽

Vol 31 (18) ◽

pp. 6046-6052 ◽

Cited By ~ 114

Author(s):

Andreas Mühlebach ◽

Scott G. Gaynor ◽

Krzysztof Matyjaszewski

Keyword(s):

Block Copolymers ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Amphiphilic Block Copolymers ◽

Atom Transfer

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