scholarly journals Confinement Assembly: Self-Assembly of Diblock Molecular Polymer Brushes in the Spherical Confinement of Nanoemulsion Droplets

2018 ◽  
Vol 39 (19) ◽  
pp. 1870046 ◽  
Author(s):  
Andrea Steinhaus ◽  
Théophile Pelras ◽  
Ramzi Chakroun ◽  
André H. Gröschel ◽  
Markus Müllner
Keyword(s):  
Self Assembly ◽  
Polymer Brushes

(PAA-g-PS)-co-PPEGMEMA asymmetric polymer brushes: synthesis, self-assembly, and encapsulating capacity for both hydrophobic and hydrophilic agents

2016 ◽  
Vol 7 (3) ◽  
pp. 613-624 ◽  
Author(s):  
Binbin Xu ◽  
Guangxin Gu ◽  
Chun Feng ◽  
Xue Jiang ◽  
Jianhua Hu ◽  
...  
Keyword(s):  
Self Assembly ◽  
Polymer Brushes ◽  
Rhodamine 6G ◽  
Aqueous Media ◽  
Large Compound

(PAA-g-PS)-co-PPEGMEMA asymmetric polymer brushes formed large compound micelles in aqueous media for encapsulating both hydrophobic pyrene and hydrophilic Rhodamine 6G.

Self-assembly of nanorod/nanoparticle mixtures in polymer brushes

2013 ◽  
Vol 52 (4) ◽  
pp. 299-309 ◽  
Author(s):  
Dong Zhang ◽  
Yankang Jin ◽  
Jun Cheng ◽  
Yangwei Jiang ◽  
Linli He ◽  
...  
Keyword(s):  
Self Assembly ◽  
Polymer Brushes

The electrostatic self-assembly of microgels on polymer brushes and its effects on interfacial friction

2016 ◽  
Vol 133 (46) ◽  
Author(s):  
Ran Zhang ◽  
Shuanhong Ma ◽  
Guoqiang Liu ◽  
Meirong Cai ◽  
Qian Ye ◽  
...  
Keyword(s):  
Self Assembly ◽  
Polymer Brushes ◽  
Interfacial Friction

Nanografting of Polymer Brushes on Gold Substrate by RAFT-RIGP

2021 ◽  
Vol 7 (1) ◽  
pp. 5
Author(s):  
Bin Jeremiah D. Barba ◽  
Patricia Nyn L. Heruela ◽  
Patrick Jay E. Cabalar ◽  
John Andrew A. Luna ◽  
Allan Christopher C. Yago ◽  
...  
Keyword(s):  
Surface Plasmon ◽  
Optical Sensors ◽  
Self Assembly ◽  
Polymer Brushes ◽  
Incident Light ◽  
Organosulfur Compounds ◽  
Layer By Layer ◽  
Label Free ◽  
Sensing Applications ◽  
Wide Range

Optical sensors based on surface plasmon resonance (SPR) have made great strides in the detection of various chemical and biological analytes. A surface plasmon is a bound, non-radiative evanescent wave generated as resonant electrons on a metal–dielectric surface to absorb energy from an incident light. As analytes bind to a functionalized metal substrate, the refractometric response generated can be used for quantitation with great selectivity, sensitivity, and capacity for label-free real-time analysis. Polymer nanobrushes are ideal recognition elements because of their greater surface area and their wide range of functional versatility. Here, we introduce a simple “grafting-from” method to covalently attach nanometer-thick polymer chains on a gold surface. Nanografting on gold-coated BK-7 glass was performed in two steps: (1) self-assembly of organosulfur compounds; and (2) RAFT-mediated radiation-induced graft polymerization (RAFT-RIGP) of polyglycidyl methacrylate (PGMA). Surface modification was monitored and verified using FTIR and SPR. Layer-by-layer thickness calculated based on Winspall 3.02 simulation fitted with experimental SPR curves showed successful self-assembly of 1-dodecanethiol (DDT) monolayer with thickness measuring 1.4 nm. These alkane chains of DDT served as the graft initiation sites for RAFT-RIGP. Nanografting was controlled by adjusting the absorbed dose in the presence of chain transfer agent, 4-cyano-4-(phenylcarbonothioylthio)pentanoic acid. The molecular weight of grafted polymers measuring 2.8 and 4.3 kDa corresponded to a thickness increase of 3.6 and 7.9 nm, respectively. These stable nanografted gold substrates may be further functionalized for sensing applications.

A Dual Functional Layer for Block Copolymer Self-Assembly and the Growth of Nanopatterned Polymer Brushes

Langmuir ◽  
2013 ◽  
Vol 29 (41) ◽  
pp. 12858-12865 ◽  
Author(s):  
Daniel P. Sweat ◽  
Myungwoong Kim ◽  
Xiang Yu ◽  
Samantha K. Schmitt ◽  
Eungnak Han ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Self Assembly ◽  
Polymer Brushes ◽  
Functional Layer ◽  
Dual Functional

Controlled Evaporative Self-Assembly of Poly(acrylic acid) in a Confined Geometry for Fabricating Patterned Polymer Brushes

Langmuir ◽  
2014 ◽  
Vol 30 (16) ◽  
pp. 4863-4867 ◽  
Author(s):  
Yonghong Men ◽  
Peng Xiao ◽  
Jing Chen ◽  
Jun Fu ◽  
Youju Huang ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Self Assembly ◽  
Polymer Brushes ◽  
Confined Geometry ◽  
Poly Acrylic Acid

scholarly journals Towards controlled polymer brushes via a self-assembly-assisted-grafting-to approach

2016 ◽  
Vol 7 (1) ◽  
Author(s):  
Tian Zhou ◽  
Hao Qi ◽  
Lin Han ◽  
Dmitri Barbash ◽  
Christopher Y. Li
Keyword(s):  
Self Assembly ◽  
Polymer Brushes

High-Density Liquid-Crystalline Polymer Brushes Formed by Surface Segregation and Self-Assembly

2016 ◽  
Vol 128 (45) ◽  
pp. 14234-14238 ◽  
Author(s):  
Koji Mukai ◽  
Mitsuo Hara ◽  
Shusaku Nagano ◽  
Takahiro Seki
Keyword(s):  
Self Assembly ◽  
Polymer Brushes ◽  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Surface Segregation ◽  
Crystalline Polymer ◽  
High Density

scholarly journals Large scale self-assembly of plasmonic nanoparticles on deformed graphene templates

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Matthew T. Gole ◽  
Zhewen Yin ◽  
Michael Cai Wang ◽  
Wayne Lin ◽  
Ziran Zhou ◽  
...  
Keyword(s):  
Self Assembly ◽  
Polymer Brushes ◽  
Large Scale ◽  
2D Materials ◽  
Plasmonic Nanoparticles ◽  
Plasmonic Nanostructures ◽  
Plasmonic Coupling ◽  
Lithographic Patterning ◽  
Assembly Method ◽  
2D Nanomaterials

AbstractHierarchical heterostructures of two-dimensional (2D) nanomaterials are versatile platforms for nanoscale optoelectronics. Further coupling of these 2D materials with plasmonic nanostructures, especially in non-close-packed morphologies, imparts new metastructural properties such as increased photosensitivity as well as spectral selectivity and range. However, the integration of plasmonic nanoparticles with 2D materials has largely been limited to lithographic patterning and/or undefined deposition of metallic structures. Here we show that colloidally synthesized zero-dimensional (0D) gold nanoparticles of various sizes can be deterministically self-assembled in highly-ordered, anisotropic, non-close-packed, multi-scale morphologies with templates designed from instability-driven, deformed 2D nanomaterials. The anisotropic plasmonic coupling of the particle arrays exhibits emergent polarization-dependent absorbance in the visible to near-IR regions. Additionally, controllable metasurface arrays of nanoparticles by functionalization with varying polymer brushes modulate the plasmonic coupling between polarization dependent and independent assemblies. This self-assembly method shows potential for bottom-up nanomanufacturing of diverse optoelectronic components and can potentially be adapted to a wide array of nanoscale 0D, 1D, and 2D materials.

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