scholarly journals Reactive Conjugated Polymers: Synthesis, Modification, and Electrochemical Properties of Polypentafluorophenylacetylene (Co)Polymers

2016 ◽  
Vol 38 (2) ◽  
pp. 1600450 ◽  
Author(s):  
Mathamsanqa N. Bhebhe ◽  
Eva Alvarez De Eulate ◽  
Yiwen Pei ◽  
Damien W. M. Arrigan ◽  
Peter J. Roth ◽  
...  
RSC Advances ◽  
2021 ◽  
Vol 11 (21) ◽  
pp. 12995-13003
Author(s):  
Jialin Yang ◽  
Li Yang ◽  
Qianqian Chen ◽  
Keke Guo ◽  
Ji-Min Han

We report a pyridine-flanked diketopyrrolopyrrole monomer and all-acceptor conjugated polymers synthesized therefrom. Photophysical, thermal and electrochemical properties of the polymers have been determined.


2018 ◽  
Vol 6 (21) ◽  
pp. 5662-5670 ◽  
Author(s):  
Bogyu Lim ◽  
Dang Xuan Long ◽  
Song-Yi Han ◽  
Yoon-Chae Nah ◽  
Yong-Young Noh

We report an effective synthetic strategy to achieve well-defined regioregular alternative conjugated polymers using large molecular weight regioregular monomers.


2012 ◽  
Vol 3 (12) ◽  
pp. 3318 ◽  
Author(s):  
Brynna J. Laughlin ◽  
William F. Baker ◽  
Tyler L. Duniho ◽  
Samantha J. El Homsi ◽  
Andrew G. Tennyson ◽  
...  

2010 ◽  
Vol 160 (11-12) ◽  
pp. 1368-1371 ◽  
Author(s):  
Wha Sun Lee ◽  
Jin Hong Park ◽  
Myung-Jin Baek ◽  
Youn-Sik Lee ◽  
Soo-Hyoung Lee ◽  
...  

2021 ◽  
Vol 9 ◽  
Author(s):  
Qiang Guo ◽  
Jincheng Zhang ◽  
Xiaoyu Li ◽  
Heqi Gong ◽  
Shuanghong Wu ◽  
...  

Over the past decades, π-conjugated polymers (CPs) have drawn more and more attention and been essential materials for applications in various organic electronic devices. Thereinto, conjugated polymers based on the 3,4-ethylenedioxythiophene (EDOT) backbone are among the high-performance materials. In order to investigate the structure–property relationships of EDOT-based polymers and further improve their electrochemical properties, a series of organic solvent–soluble EDOT-based alternative copolymers consisting of electron-rich fragments (fluorene P1, carbazole P2, and 3,4-alkoxythiophene P3) or electron-deficient moieties (benzotriazole P4 and thieno[3,4-c]pyrrole-4,6-dione P5) were synthesized via direct C–H (hetero)arylation polymerization (DHAP) in moderate to excellent yields (60–98%) with medium to high molecular weights (Mn = 3,100–94,000 Da). Owing to their various electronic and structural properties, different absorption spectra (λmax = 476, 380, 558, 563, and 603 nm) as well as different specific capacitances of 70, 68, 75, 51, and 25 F/g with 19, 10, 21, 26, and 69% of capacity retention after 1,000 cycles were observed for P1–P5, respectively. After careful study through multiple experimental measurements and theoretical calculation, appropriate electronic characteristics, small molecular conformation differences between different oxidative states, and well-ordered molecular stacking could improve the electrochemical performance of CPs.


Polymer ◽  
2010 ◽  
Vol 51 (13) ◽  
pp. 2897-2902 ◽  
Author(s):  
Jian Chen ◽  
Min-Min Shi ◽  
Xiao-Lian Hu ◽  
Mang Wang ◽  
Hong-Zheng Chen

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