Individually Addressable Thermo- and Redox-Responsive Block Copolymers by Combining Anionic Polymerization and RAFT Protocols

2014 ◽  
Vol 35 (7) ◽  
pp. 708-714 ◽  
Author(s):  
Bernhard V. K. J. Schmidt ◽  
Johannes Elbert ◽  
Christopher Barner-Kowollik ◽  
Markus Gallei
Keyword(s):  
Block Copolymers ◽  
Anionic Polymerization ◽  
Redox Responsive

Synthesis of (meth)acrylate Block Copolymers by Ligated Anionic Polymerization

2006 ◽  
Vol 240 (1) ◽  
pp. 141-150 ◽  
Author(s):  
Petr Vlček ◽  
Eva Čadová ◽  
Miroslav Janata ◽  
Petra Látalová ◽  
Luděk Toman ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Anionic Polymerization

Anionic polymerization of activated oxetane and its copolymerization with ethylene oxide for the synthesis of amphiphilic block copolymers

2018 ◽  
Vol 9 (19) ◽  
pp. 2660-2668 ◽  
Author(s):  
Matthieu Gervais ◽  
Antoine Forens ◽  
Emmanuel Ibarboure ◽  
Stephane Carlotti
Keyword(s):  
Block Copolymers ◽  
Ethylene Oxide ◽  
Anionic Polymerization ◽  
Triblock Copolymers ◽  
Amphiphilic Block Copolymers ◽  
Tetraoctylammonium Bromide

The anionic polymerization of oxetane in toluene was achieved using a combination of tetraoctylammonium bromide and simple triisobutylaluminum. By its copolymerization with ethylene oxide, di- and triblock copolymers were prepared in one and two steps respectively.

scholarly journals A controlled synthesis method of alkyl methacrylate block copolymers via living anionic polymerization at ambient temperature

RSC Advances ◽  
2019 ◽  
Vol 9 (28) ◽  
pp. 16049-16056 ◽  
Author(s):  
Zheng Li ◽  
Jianding Chen ◽  
Guijin Zou ◽  
Tongyuan Zhang ◽  
Dafu Wei ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Ambient Temperature ◽  
Anionic Polymerization ◽  
Diblock Copolymers ◽  
Synthesis Method ◽  
Controlled Synthesis ◽  
Living Anionic Polymerization ◽  
Alkyl Methacrylate ◽  
High Yields

A series of well-defined diblock copolymers containing PMMA, PEMA and PBMA blocks were synthesized with narrow MWDs and high yields via anionic polymerization, while t-BuOK was selected as initiator in THF at 0 °C. .

Self-assembly and disassembly of a redox-responsive ferrocene-containing amphiphilic block copolymer for controlled release

2015 ◽  
Vol 6 (10) ◽  
pp. 1817-1829 ◽  
Author(s):  
Lichao Liu ◽  
Leilei Rui ◽  
Yun Gao ◽  
Weian Zhang
Keyword(s):  
Controlled Release ◽  
Block Copolymer ◽  
Block Copolymers ◽  
Rhodamine B ◽  
Self Assembly ◽  
Amphiphilic Block Copolymer ◽  
Model Molecule ◽  
Redox Responsive

The synthesis and self-assembly of ferrocene-containing block copolymers PEG-b-PMAEFc, and the encapsulation and redox-responsive release of a model molecule (rhodamine B) upon external redox stimuli (H2O2).

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