High-Performance Exfoliated Poly(propylene)/Clay Nanocomposites by In Situ Polymerization with a Novel Z–N/Clay Compound Catalyst

2007 ◽  
Vol 28 (24) ◽  
pp. 2294-2299 ◽  
Author(s):  
Kai Du ◽  
Aihua H. He ◽  
Xin Liu ◽  
Charles C. Han
Author(s):  
Xiaojuan Shen ◽  
Xuan Zhang ◽  
Tongfei Wang ◽  
Songjun Li ◽  
Zhaoqiang Li

In this study, a novel 3D porous Si-based supercapacitor electrode was developed by the simple solution method, which involved firstly the in-situ polymerization of polyaniline particles (PANI) on the Si...


2019 ◽  
Vol 361 ◽  
pp. 897-907 ◽  
Author(s):  
Jingchun Lv ◽  
Peiwen Zhou ◽  
Linping Zhang ◽  
Yi Zhong ◽  
Xiaofeng Sui ◽  
...  

2008 ◽  
Vol 41 (16) ◽  
pp. 6035-6040 ◽  
Author(s):  
Mehmet Atilla Tasdelen ◽  
Wim Van Camp ◽  
Eric Goethals ◽  
Philippe Dubois ◽  
Filip Du Prez ◽  
...  

2014 ◽  
Vol 983 ◽  
pp. 39-43
Author(s):  
M. A. Alaa ◽  
Kamal Yusoh ◽  
S.F. Hasany

Petroleum based polyurethanes are contributing major portions in the world requirement. To overcome the environmental issues and price adaptability, there is always a massive demand of utilization of renewable resources for polyurethane synthesis with comparable physico-chemical properties. Castor oil is the only major natural vegetable oil that contains a hydroxyl group (-OH) and unsaturated double bonds (C=C) in its organic chain and therefore can be employed with or without modification due to the excellent properties derived from the hydrophobic nature of triglycerides. In this study, physico-chemical properties of high performance polyurethane synthesized from Poly propylene glycol (PPG) in comparison with a combination of PPG and Castor oil (a renewable source), by in situ polymerization technique has been studied. The variations in properties of both types of polyurethanes are evaluated by Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM) and Thermogravimetric analysis technique (TGA). Tensile strength properties were investigated by Film Tensile testing equipment. Results indicated the presence of large-CH stretching in castor oil mixed polyurethane with a larger oxidative thermal stability, over a pure PPG polyurethanes. Tensile properties were found almost comparable in pure and mixed polymers, which signify the usage of mixed polymer in coming future, to overcome the environmental and economical crisis in polyurethanes synthesis.


Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 985 ◽  
Author(s):  
Yidong Liu ◽  
Lingfeng Jian ◽  
Tianhua Xiao ◽  
Rongtao Liu ◽  
Shun Yi ◽  
...  

CO2 has been regarded as one of the most promising blowing agents for polystyrene (PS) foam due to its non-flammability, low price, nontoxicity, and eco-friendliness. However, the low solubility and fast diffusivity of CO2 in PS hinder its potential applications. In this study, an attapulgite (ATP)/polypyrrole (PPy) nanocomposite was developed using the in situ polymerization method to generate the hierarchical cell texture for the PS foam based on the supercritical CO2 foaming. The results demonstrated that the nanocomposite could act as an efficient CO2 capturer enabling the random release of it during the foaming process. In contrast to the pure PS foam, the ATP/PPy nanocomposite reinforced PS foam is endowed with high cell density (up to 1.9 × 106) and similar thermal conductivity as the neat PS foam, as well as high compression modulus. Therefore, the in situ polymerized ATP/PPy nanocomposite makes supercritical CO2 foaming desired candidate to replace the widely used fluorocarbons and chlorofluorocarbons as PS blowing agents.


2014 ◽  
Vol 989-994 ◽  
pp. 164-167
Author(s):  
Rui Feng

An in-situ polymerization method was used for the preparation of a novel stir bar based on neodymium magnet (Nd2Fe14B) powders. The processes were carried out by several steps including the enwrapping of Nd2Fe14B, the modification of the enclosed Nd2Fe14B, and the form of organic polymers on the surface of the modified powders. It was successfully used to enrich the plasticizers in water sample by stir bar sorptive extraction (SBSE). The experimental conditions for SBSE, such as the choice of extraction sorvents, salt concentration, extraction and desorption time were optimized in detail. Coupled to high performance liquid chromatography (HPLC), the recoveries of dibutyl phthalate (DBP), dimethyl phthalate (DMP), diethyl phthalate (DEP) were 89.2%~92.1%, 91.9%~96.6% and 94.3%~96.7%, respectively; the linear relationships between the concentration 5 μg/L and 800 μg/L for DBP were obtained; the limits of detection ranged from 0.09 μg/L to 0.21 μg/L in the optimal conditions.


RSC Advances ◽  
2020 ◽  
Vol 10 (73) ◽  
pp. 44688-44698
Author(s):  
Yulin Jiang ◽  
Jiawen Ji ◽  
Leping Huang ◽  
Chengen He ◽  
Jinlong Zhang ◽  
...  

Efficient ball-milling production of graphene/polyaniline composites as supercapacitor electrodes with enhanced capacitive contribution, rate capability, and specific capacitance.


Sign in / Sign up

Export Citation Format

Share Document