Transparent Surfactant/Epoxy Composite Coatings with Self‐Healing and Superhydrophilic Properties

2019 ◽  
Vol 304 (7) ◽  
pp. 1800765 ◽  
Author(s):  
Wei Li ◽  
Gang Wu ◽  
Jinhui Tan ◽  
Xufeng Yu ◽  
Gang Sun ◽  
...  
Metals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 704
Author(s):  
Marija Riđošić ◽  
Nebojša D. Nikolić ◽  
Asier Salicio-Paz ◽  
Eva García-Lecina ◽  
Ljiljana S. Živković ◽  
...  

Electrodeposition and characterization of novel ceria-doped Zn-Co composite coatings was the main goal of this research. Electrodeposited composite coatings were compared to pure Zn-Co coatings obtained under the same conditions. The effect of two ceria sources, powder and home-made sol, on the morphology and corrosion resistance of the composite coatings was determined. During the electrodeposition process the plating solution was successfully agitated in an ultrasound bath. The source of the particles was found to influence the stability and dispersity of plating solutions. The application of ceria sol resulted in an increase of the ceria content in the resulting coating and favored the refinement from cauliflower-like morphology (Zn-Co) to uniform and compact coral-like structure (Zn-Co-CeO2 sol). The corrosion resistance of the composite coatings was enhanced compared to bare Zn-Co as evidenced by electrochemical impedance spectroscopy and scanning Kelvin probe results. Zn-Co doped with ceria particles originating from ceria sol exhibited superior corrosion resistance compared to Zn-Co-CeO2 (powder) coatings. The self-healing rate of artificial defect was calculated based on measured Volta potential difference for which Zn-Co-CeO2 (sol) coatings exhibited a self-healing rate of 73.28% in a chloride-rich environment.


2021 ◽  
Vol 157 ◽  
pp. 106283
Author(s):  
Yanxuan Ma ◽  
Jiatong Liu ◽  
Yingrui Zhang ◽  
Yajie Ge ◽  
Rui Wu ◽  
...  

Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 179
Author(s):  
M. M. A. Baig ◽  
M. Abdul Samad

Epoxy composite coating systems generally find their usage in applications such as, fluid handling systems to protect components from corrosive media. However, their use in demanding tribological applications such as, in sliding components of machines, are known to be limited. This is often attributed to their low load bearing capacity combined with poor thermal stability under severe p-v regimes. Researchers have tried to enhance the tribological properties of the epoxy coatings using a combination of several types of micro/nano sized fillers to produce composite or hybrid composite coatings. Hence, this review paper aims to focus on the recent advances made in developing the epoxy coating systems. Special attention would be paid to the types and properties of nano-fillers that have been commonly used to develop these coatings, different dispersion techniques adopted and the effects that each of these fillers (and their combinations) have on the tribological properties of these coatings.


2019 ◽  
Vol 129 ◽  
pp. 285-291 ◽  
Author(s):  
Jing Li ◽  
Zhenwei Li ◽  
Qingkang Feng ◽  
Hanxun Qiu ◽  
Guangzhi Yang ◽  
...  

2019 ◽  
Vol 6 (9) ◽  
pp. 0950a8
Author(s):  
She Jia ◽  
Zhengjun Yao ◽  
Shasha Zhang ◽  
Zelei Zhang ◽  
Xuewei Tao ◽  
...  

Author(s):  
Muddasir Nawaz ◽  
Sehrish Habib ◽  
Adnan Khan ◽  
Abdul Shakoor ◽  
Ramazan Kahraman

The use of organic coating for the metals has been widely being used to protect the surface against corrosion. Polymeric coating incorporated with Nanocontainers loaded with inhibitor and self-healing provides better corrosion resistance. Cellulose microfibers (CMFs) used as smart carriers were synthesized and loaded with dodecylamine (DOC)-inhibitor and polyethyleneimine (PEI)-both inhibitor and self-healing agents. Smart polymeric coatings were developed by mixing CMF/DOC and CMFs/PEI into the epoxy matrix. Reference coatings (that has only CMFs) were also prepared for a compersion. Scanning electron microscope (SEM), X-ray diffraction spectroscopy (XRD), Fourier transform infrared spectroscopy (FTIR) and thermal gravitational analysis (TGA) were used to confirm the loading of DOC and PEI onto the CMFs. UV-vis analysis indicates that the self-release of inhibitor from CMFs is sensitive to pH of the solution and the immersion time. Recovery of controlled surface damage confirms the decent self-healing ability of the prepared smart coatings is due to the efficient release of inhibitor (DOC) and self-healing agent (PEI) in the damaged area leading to the formation of a protective film. Electrochemical impedance spectroscopy (EIS) results demonstrate that corrosion resistance of the smart coating increases with an increase in immersion time which is due to the progressive release of inhibitors from CMFs in response to the pH change. Therefore, smart coatings demonstrate superior properties as compared to the reference coatings. The study reveals the polymeric composite coatings have potential to inhibit the corrosion of steel for oil and gas industry.


2015 ◽  
Vol 245 ◽  
pp. 89-96 ◽  
Author(s):  
Andrey S. Gnedenkov ◽  
Sergey L. Sinebryukhov ◽  
Dmitry V. Mashtalyar ◽  
Sergey V. Gnedenkov

The way of self-healing coating formation at the surface of magnesium alloys by means of plasma electrolytic oxidation method (PEO) with subsequent filling of the obtained layer with inhibitor has been suggested. The electrochemical properties of such coatings have been described in details. The obtained experimental results indicate that the protective properties of the samples with inhibitor-containing coating were increased (IC = 8.6×10–8 A/cm2) in comparison with the samples without coating (5.3×10–5 A/cm2) and the base coating obtained by plasma electrolytic oxidation method (PEO) (3.4×10–7 A/cm2). The local scanning electrochemical methods of surface investigation, notably Scanning Vibrating Electrode Technique (SVET) and Scanning Ion-Selective Electrode Technique (SIET) were used for determining the kinetics and mechanism of the self-healing process. The treatment by the solution containing 8-hydroxyquinoline, which inhibits the corrosion process, enables one to increase the protective properties of the composite coating in 30 times in the corrosion-active environment in comparison with the base PEO-coating and avert the intensive destruction of the material.


2021 ◽  
pp. 110957
Author(s):  
Shaoxiang Li ◽  
Feifan Du ◽  
Yanxu Lin ◽  
Yu Guan ◽  
WenJuan Qu ◽  
...  

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