Solvated Ionic‐Liquid Incorporated Soft Flexible Cross‐Linked Network Polymer Electrolytes for Safer Lithium Ion Secondary Batteries

2021 ◽  
pp. 2100317
Author(s):  
Manjit Singh Grewal ◽  
Manabu Tanaka ◽  
Hiroyoshi Kawakami
Keyword(s):  
Ionic Liquid ◽  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Network Polymer

Lithium-Containing Zwitterionic Poly(Ionic Liquid)s as Polymer Electrolytes for Lithium-Ion Batteries

2017 ◽  
Vol 121 (33) ◽  
pp. 17756-17763 ◽  
Author(s):  
Fei Lu ◽  
Xinpei Gao ◽  
Aoli Wu ◽  
Na Sun ◽  
Lijuan Shi ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Lithium Ion Batteries ◽  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Poly Ionic Liquid

Single lithium-ion polymer electrolytes based on poly(ionic liquid)s for lithium-ion batteries

Soft Matter ◽  
2018 ◽  
Vol 14 (30) ◽  
pp. 6313-6319 ◽  
Author(s):  
Yang Yu ◽  
Fei Lu ◽  
Na Sun ◽  
Aoli Wu ◽  
Wei Pan ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Lithium Ion Batteries ◽  
Lithium Batteries ◽  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Ion Conductor ◽  
Li Ion ◽  
Poly Ionic Liquid ◽  
Transport Channels

A novel single Li-ion conductor based on poly(ionic liquid)s provides Li+-rich transport channels for lithium batteries.

scholarly journals Plasticized 3D-Printed Polymer Electrolytes for Lithium-Ion Batteries

2021 ◽  
Author(s):  
Adi Vinegrad ◽  
Heftsi Ragones ◽  
Nishani Jayakodi ◽  
Gilat Ardel ◽  
Meital Goor ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Fused Filament Fabrication ◽  
Free Standing ◽  
Show Evidence ◽  
Order Of Magnitude ◽  
3D Printed

Abstract In the current research, we developed and printed by fused-filament fabrication polylactide-polyethylene-oxide blended membranes. The influence of relative content of polymers on the ease of extrusion and printing processes was studied. Ionic liquid N-butyl-N-methylpyrrolidinium bis(trifluoromethane-sulfonyl)imide (Pyr14TFSI) with dissolved LiTFSI salt was infused into the membranes to produce free-standing films of quasi-solid polymer electrolytes. The printed membranes were characterized by ESEM, DSC, XPS, NMR and EIS methods. Neat-printed PLA membrane exhibited poor wetting and low uptake of ionic liquid. However, the XPS tests of 3D-printed PLA-PEO membrane infused with LiTFSI solvated ionic liquid show evidence of the interaction between lithium cations with both, PEO and PLA. The measurements of diffusion coefficients by PGSE-NMR suggest that the Li+ ions are coordinated by the PEO segments in the polymer blend. Increase of the PEO content at the expense of PLA polymer, leads to more than one order of magnitude improvement of bulk conductivity, approaching 0.2mS/cm at 60℃.

scholarly journals Headway in rhodanide anion based ternary gel polymer electrolytes (TILGPEs) for applications in rechargeable lithium ion batteries: an efficient route to achieve high electrochemical and cycling performances

RSC Advances ◽  
2017 ◽  
Vol 7 (31) ◽  
pp. 19211-19222 ◽  
Author(s):  
K. Karuppasamy ◽  
K. Prasanna ◽  
Dongkyu Kim ◽  
Yong Hee Kang ◽  
Hee Woo Rhee
Keyword(s):  
Ionic Liquid ◽  
Lithium Ion Batteries ◽  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Gel Polymer Electrolytes ◽  
Efficient Route ◽  
First Time ◽  
Cycling Performances

For the first time, a new category of rhodanide anion based ternary ionic liquid gel polymer electrolytes has been synthesized and characterized for its applications in lithium ion batteries.

Preparation of a ROMP-type imidazolium-functionalized norbornene ionic liquid block copolymer and the electrochemical property for lithium-ion batteries polyelectrolyte membranes

RSC Advances ◽  
2015 ◽  
Vol 5 (54) ◽  
pp. 43581-43588 ◽  
Author(s):  
Juan Wang ◽  
Xiaohui He ◽  
Hongyu Zhu ◽  
Defu Chen
Keyword(s):  
Ionic Liquid ◽  
Block Copolymer ◽  
Ionic Conductivity ◽  
Lithium Ion Batteries ◽  
Electrochemical Property ◽  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Polyelectrolyte Membranes

Solid polymer electrolytes with high ionic conductivity have been prepared based on an imidazolium-functionalized norbornene ionic liquid block copolymer.

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