Radiation Synthesis of Rapidly Self‐Healing Hydrogel Derived from Poly(acrylic acid) with Good Mechanical Strength

2020 ◽  
Vol 221 (19) ◽  
pp. 2000218
Author(s):  
Mohamed Mohamady Ghobashy ◽  
Nour E. A. Abd El‐Sattar
2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Jaebin Nam ◽  
Eunsoo Kim ◽  
Rajeev K.K. ◽  
Yeonho Kim ◽  
Tae-Hyun Kim

Abstract A ureido-pyrimidinone (UPy)-functionalized poly(acrylic acid) grafted with poly(ethylene glycol)(PEG), designated PAU-g-PEG, was developed as a high performance polymer binder for Si anodes in lithium-ion batteries. By introducing both a ureido-pyrimidinone (UPy) unit, which is capable of self-healing through dynamic hydrogen bonding within molecules as well as with Si, and an ion-conducting PEG onto the side chain of the poly(acrylic acid), this water-based self-healable and conductive polymer binder can effectively accommodate the volume changes of Si, while maintaining electronic integrity, in an electrode during repeated charge/discharge cycles. The Si@PAU-g-PEG electrode retained a high capacity of 1,450.2 mAh g−1 and a Coulombic efficiency of 99.4% even after 350 cycles under a C-rate of 0.5 C. Under a high C-rate of 3 C, an outstanding capacity of 2,500 mAh g−1 was also achieved, thus demonstrating its potential for improving the electrochemical performance of Si anodes.


2018 ◽  
Vol 10 (12) ◽  
pp. 1813-1822 ◽  
Author(s):  
Guihua Li ◽  
Xingxiang Ji ◽  
Jinhuan Sun ◽  
Zaiwu Yuan ◽  
Yuexia Wang

2004 ◽  
Vol 69 (6) ◽  
pp. 481-486 ◽  
Author(s):  
Sanju Francis ◽  
Manmohan Kumar ◽  
Lalit Varshney

Soft Matter ◽  
2019 ◽  
Vol 15 (37) ◽  
pp. 7381-7389 ◽  
Author(s):  
Rui Zhang ◽  
Hengzhi Ruan ◽  
Tianxu Zhou ◽  
Qionglong Fu ◽  
Hongwei Peng ◽  
...  

Two block copolymers containing amino-acid derivatives were employed as a macro-crosslinker to prepare high performance PAA hydrogels concluding desirable mechanical properties and self-healing abilities, as well as notch-insensitivity.


2003 ◽  
Vol 67 (6) ◽  
pp. 745-749 ◽  
Author(s):  
G.A. Mun ◽  
Z.S. Nurkeeva ◽  
V.V. Khutoryanskiy ◽  
B.B. Yermukhambetova ◽  
S.M. Koblanov ◽  
...  

2015 ◽  
Vol 1092-1093 ◽  
pp. 852-855
Author(s):  
Xiao Dan Lv ◽  
Zheng Yang Wang ◽  
Jian Hui Zhang ◽  
Zi Shu Chen ◽  
Wei Feng Cao ◽  
...  

A novel hydrogel was successfully synthesized through doping 4A molecular sieve (4A-MS) into poly (acrylic acid-co-acrylamide) and used for the removal of Cu2+, Ni2+, Cd2+and Pb2+in the solution. The composite hydrogel all exhibited high sorption capacity (SC) and high elution percentage (EP) for the four above heavy metal ions. Simultaneously, the water uptake (WU) of the hydrogel was dramatically decreased and the mechanical strength of the absorbent hydrogel was improved with increasing 4A-MS content.


2020 ◽  
Vol 31 (7) ◽  
pp. 1648-1660 ◽  
Author(s):  
Tingting Li ◽  
Xiangming Hu ◽  
Qingsong Zhang ◽  
Yanyun Zhao ◽  
Peng Wang ◽  
...  

2013 ◽  
Vol 4 (17) ◽  
pp. 4601 ◽  
Author(s):  
Zengjiang Wei ◽  
Jie He ◽  
Tony Liang ◽  
Hyuntaek Oh ◽  
Jasmin Athas ◽  
...  

1998 ◽  
Vol 37 (6) ◽  
pp. 354-358 ◽  
Author(s):  
Xiangling Xu ◽  
Yadong Yin ◽  
Xuewu Ge ◽  
Hongkai Wu ◽  
Zhicheng Zhang

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