Impact of Catalyst on the Stability of Initiators on Au Substrate in Atom Transfer Radical Polymerization

2014 ◽  
Vol 215 (21) ◽  
pp. 2060-2064 ◽  
Author(s):  
Yongming Tang ◽  
Richard O. Osibanjo ◽  
Jessica Moore ◽  
Elyse N. Towns ◽  
Tonya L. Kuhl ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
The Stability

Functionalization of Carbon Particles by Atom Transfer Radical Polymerization

MRS Advances ◽  
2017 ◽  
Vol 2 (47) ◽  
pp. 2537-2544
Author(s):  
Nurettin Sahiner ◽  
Sultan B Sengel
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Trimethylammonium Chloride ◽  
Carbon Particles ◽  
Temperature Responsive ◽  
Spherical Carbon ◽  
The Stability ◽  
Post Modification ◽  
Controllable Size

ABSTRACTSpherical carbon particles (CPs) with controllable size and surface functionalities were prepared via hydrothermal treatment using sucrose as a precursor and then post modification methods. The CPs were prepared in two steps; firstly, dewatering of sucrose molecules at relatively low temperatures and secondly, carbonization at high temperatures. The micro/nano-sized CPs were functionalized by 2-Acrylamido-2-methylpropane sulfonic acid (AMPS), (3-Acrylamidopropyl)-trimethylammonium chloride (APTMACI), and N-isopropylacrylamide (NIPAM) in order to have the corresponding polymers on the surface of CPs. The monomers were polymerized via atom transfer radical polymerization (ATRP) by means of grafted initiator onto the CPs surface. Additionally, copolymer of these monomers was synthesized to introduce additional properties. The stability of the functionalized CPs in different solutions, and pH, temperature responsive behaviors of the newly prepared CP-polymers composite were evaluated.

Redox Responsive Behavior of Thiol/Disulfide-Functionalized Star Polymers Synthesized via Atom Transfer Radical Polymerization

2010 ◽  
Vol 43 (9) ◽  
pp. 4133-4139 ◽  
Author(s):  
Jun Kamada ◽  
Kaloian Koynov ◽  
Cathrin Corten ◽  
Azhar Juhari ◽  
Jeong Ae Yoon ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Star Polymers ◽  
Atom Transfer ◽  
Redox Responsive ◽  
Responsive Behavior

Simplified Electrochemically Mediated Atom Transfer Radical Polymerization using a Sacrificial Anode

2015 ◽  
Vol 54 (8) ◽  
pp. 2388-2392 ◽  
Author(s):  
Sangwoo Park ◽  
Paweł Chmielarz ◽  
Armando Gennaro ◽  
Krzysztof Matyjaszewski
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Sacrificial Anode
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